Reactions between macrocyclic nickel(II) complexes and ferricyanide.: Metamagnetic properties of a two-dimensional honeycomb assembly [NiL3]3[Fe(CN)6]2•8H2O (L3=3,10-dihydroxyethyl-1,3,6,8,10,12-hexaazacyclotetradecane)

被引：61
作者：
Kou, HZ [1 ]
Bu, WM
Gao, S
Liao, DZ
Jiang, ZH
Yan, SP
Fan, YG
Wang, GL
机构：
[1] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
[2] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[3] Jilin Univ, Key Lab Supramol Struct & Spect, Changchun 130023, Peoples R China
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 17期
关键词：
D O I：
10.1039/b003289l
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, structural and magnetic properties of the 2-D bimetallic complex [NiL3](3)[Fe(CN)(6)](2). 8H(2)O (L-3=3,10-dihydroxyethyl-1,3,6,8,10,12-hexaazacyclotetradecane) are presented. The structure consists of cyano-bridged neutral honeycomb-like layers. Each hexacyanoferrate(III) ion connects three nickel(II) ions using three cis CN- groups and the remaining CN- groups are terminal. The bridging cyanide ligands coordinate to the nickel ion in a trans fashion. Magnetic studies showed that the complex displays a metamagnetic behaviour arising from intralayer ferromagnetic coupling and interlayer antiferromagnetic interactions. A long-range magnetic ordering at T-c=6.0 K was observed. In addition, the ionic complex [NiL4](3)[Fe(CN)(6)](2). 6H(2)O (L-4=8-methyl-1,3,6,8,10,13,15-heptaazatricyclo[13.1.1.1(13,15)]octadecane) showing the absence of cyano bridging, is reported.
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页码：2996 / 3000
页数：5
相关论文
共 63 条
  • [31] Langenberg K. V., 1997, INORG CHEM, V36, P5006
  • [32] Structure, ferromagnetic ordering, anisotropy, and spin reorientation for the two-dimensional cyano-bridged bimetallic compound K2Mn3(H2O)6[Mo(CN)7]2•6H2O
    Larionova, J
    Kahn, O
    Gohlen, S
    Ouahab, L
    Clérac, R
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) : 3349 - 3356
  • [33] Crystal structure, ferromagnetic ordering and magnetic anisotropy for two cyano-bridged bimetallic compounds of formula Mn2(H2O)5Mo(CN)7•nH2O
    Larionova, J
    Sanchiz, J
    Gohlen, S
    Ouahab, L
    Kahn, O
    [J]. CHEMICAL COMMUNICATIONS, 1998, (09) : 953 - 954
  • [34] Ferromagnetic ordering, anisotropy, and spin reorientation for the cyano-bridged bimetallic compound Mn2(H2O)5Mo(CN)7•4H2O (α phase)
    Larionova, J
    Clérac, R
    Sanchiz, J
    Kahn, O
    Golhen, S
    Ouahab, L
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (50) : 13088 - 13095
  • [35] Lu TB, 2000, CHEM J CHINESE U, V21, P187
  • [36] HIGH-T(C) MOLECULAR-BASED MAGNETS - FERRIMAGNETIC MIXED-VALENCE CHROMIUM(III)-CHROMIUM(II) CYANIDES WITH T(C) AT 240-KELVIN AND 190-KELVIN
    MALLAH, T
    THIEBAUT, S
    VERDAGUER, M
    VEILLET, P
    [J]. SCIENCE, 1993, 262 (5139) : 1554 - 1557
  • [37] Ferromagnetic order in a μ-cyano CrIII-MnII assembly with an unusual branched architecture
    Marvilliers, A
    Parsons, S
    Rivière, E
    Audière, JP
    Mallah, T
    [J]. CHEMICAL COMMUNICATIONS, 1999, (21) : 2217 - 2218
  • [38] Matsumoto N, 1999, ANGEW CHEM INT EDIT, V38, P171, DOI 10.1002/(SICI)1521-3773(19990115)38:1/2<171::AID-ANIE171>3.0.CO
  • [39] 2-U
  • [40] THE 2-DIMENSIONAL NETWORK STRUCTURE AND METAMAGNETIC PROPERTIES OF THE 2/1 COMPLEX OF [MN(3-MEOSALEN)(H2O)]CLO4 AND K-3[FE(CN)(6)]
    MIYASAKA, H
    MATSUMOTO, N
    OKAWA, H
    RE, N
    GALLO, E
    FLORIANI, C
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (13-14): : 1446 - 1448
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