Adsorption behavior of copper ions from aqueous solution onto graphene oxide-CdS composite

被引：112
作者：
Jiang, Tingshun [1 ]
Liu, Wangping [1 ]
Mao, Yulin [1 ]
Zhang, Lei [1 ]
Cheng, Jinlian [1 ]
Gong, Ming [1 ]
Zhao, Haibo [1 ]
Dai, Liming [1 ]
Zhang, Shuai [1 ]
Zhao, Qian [1 ]
机构：
[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China
来源：
CHEMICAL ENGINEERING JOURNAL | 2015年 / 259卷
关键词：
Graphene oxide; CdS; Ethylenediamine; Adsorption; Copper ions; HEAVY-METALS; WASTE-WATER; CHEMICAL-REDUCTION; REMOVAL; CHROMIUM; COBALT; ADSORBENTS; NANOSHEETS; NANORODS; ZN(II);
D O I：
10.1016/j.cej.2014.08.022
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Graphene oxide (GO)-CdS composite (GO/CdS(en)) is prepared by liquid insertion method with addition of ethylenediamine (en) in synthesis process. The properties of the composite are characterized by FT-IR, XRD, TEM, Raman spectroscopy and N-2 physical adsorption, respectively. The adsorption capacity of the composite was evaluated by the removal of copper ions from aqueous solution. Effect of several factors including the initial pH, absorbent dose and contact time on removal efficiency of copper ions was investigated by batch experiment. The results show that the GO/CdS(en) composite exhibits excellent adsorption capacity for Cu(II) ions and has good chemical stability. Under the optimum experimental conditions, the removal rate of copper ions can reach ca. 90%. Also, the adsorption isotherm was investigated by both Langmuir and Freundlich models. The adsorption process was found to be well-described by Langmuir model. Thermodynamics parameters suggest that Cu(II) ions adsorption on the GO/CdS(en) was an endothermic and spontaneous process. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：603 / 610
页数：8
相关论文
共 48 条
[41]   Use of iron oxide nanomaterials in wastewater treatment: A review [J].
Xu, Piao ;
Zeng, Guang Ming ;
Huang, Dan Lian ;
Feng, Chong Ling ;
Hu, Shuang ;
Zhao, Mei Hua ;
Lai, Cui ;
Wei, Zhen ;
Huang, Chao ;
Xie, Geng Xin ;
Liu, Zhi Feng .
SCIENCE OF THE TOTAL ENVIRONMENT, 2012, 424 :1-10
[42]   Oxidation and disorder in few-layered graphene induced by the electron-beam irradiation [J].
Xu, Zhiwei ;
Chen, Lei ;
Li, Jialu ;
Wang, Rui ;
Qian, Xiaoming ;
Song, Xiaoyan ;
Liu, Liangsen ;
Chen, Guangwei .
APPLIED PHYSICS LETTERS, 2011, 98 (18)
[43]   Folding/aggregation of graphene oxide and its application in Cu2+ removal [J].
Yang, Sheng-Tao ;
Chang, Yanli ;
Wang, Haifang ;
Liu, Gangbo ;
Chen, Sheng ;
Wang, Yanwen ;
Liu, Yuanfang ;
Cao, Aoneng .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 351 (01) :122-127
[44]   Adsorption behavior of copper ions on graphene oxide-chitosan aerogel [J].
Yu, Baowei ;
Xu, Jing ;
Liu, Jia-Hui ;
Yang, Sheng-Tao ;
Luo, Jianbin ;
Zhou, Qinghan ;
Wan, Jing ;
Liao, Rong ;
Wang, Haifang ;
Liu, Yuanfang .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2013, 1 (04) :1044-1050
[45]   REMOVAL OF HEAVY-METALS AND OTHER CATIONS FROM WASTE-WATER USING ZEOLITES [J].
ZAMZOW, MJ ;
EICHBAUM, BR ;
SANDGREN, KR ;
SHANKS, DE .
SEPARATION SCIENCE AND TECHNOLOGY, 1990, 25 (13-15) :1555-1569
[46]   Few-Layered Graphene Oxide Nanosheets As Superior Sorbents for Heavy Metal Ion Pollution Management [J].
Zhao, Guixia ;
Li, Jiaxing ;
Ren, Xuemei ;
Chen, Changlun ;
Wang, Xiangke .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (24) :10454-10462
[47]   Removal of Pb(II) ions from aqueous solutions on few-layered graphene oxide nanosheets [J].
Zhao, Guixia ;
Ren, Xuemei ;
Gao, Xing ;
Tan, Xiaoli ;
Li, Jiaxing ;
Chen, Changlun ;
Huang, Yuying ;
Wang, Xiangke .
DALTON TRANSACTIONS, 2011, 40 (41) :10945-10952
[48]   Sulfonated Graphene for Persistent Aromatic Pollutant Management [J].
Zhao, Guixia ;
Jiang, Lang ;
He, Yudong ;
Li, Jiaxing ;
Dong, Huanli ;
Wang, Xiangke ;
Hu, Wenping .
ADVANCED MATERIALS, 2011, 23 (34) :3959-+
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