Recent advances in the transition metal catalyzed synthesis of quinoxalines: a review

被引:46
作者
Maikhuri, Vipin K. [1 ]
Prasad, Ashok K. [1 ]
Jha, Amitabh [2 ]
Srivastava, Smriti [2 ]
机构
[1] Univ Delhi, Dept Chem, Bioorgan Lab, Delhi 110007, India
[2] Acadia Univ, Dept Chem, Wolfville, NS B4P 2R6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
ONE-POT SYNTHESIS; CROSS-COUPLING REACTIONS; C-H ACTIVATION; REUSABLE CATALYST; DERIVATIVES; HYDROGENATION; ANNULATION; EFFICIENT; COPPER; BENZIMIDAZOLES;
D O I
10.1039/d1nj01442k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Quinoxalines are a class of N-heterocycles which are present in a variety of natural and synthetic compounds. They act as a versatile building block in synthesizing novel heterocyclic scaffolds and are important intermediates in many bioactive compounds. They have achieved immense significance in organic as well as medicinal chemistry. Several synthetic approaches have been developed to afford a variety of quinoxaline derivatives. In this review, we have summarized the recent progress in the transition metal-catalyzed synthesis of quinoxalines.
引用
收藏
页码:13214 / 13246
页数:33
相关论文
共 138 条
  • [1] Fe3O4@FeSO4-MCM-41 Nanoparticles and Reusable Catalyst for the Synthesis of Quinoxalines in Solvent-free Conditions
    Abadi, Seyed Shahab Addin Darbandizadeh Mohammad
    Abdollahi-Alibeik, Mohammad
    [J]. SILICON, 2018, 10 (04) : 1667 - 1678
  • [2] Copper-catalyzed tandem aerobic oxidative cyclization for the synthesis of 4-cyanoalkylpyrrolo[1,2-a]quinoxalines from 1-(2-aminophenyl)pyrroles and cyclobutanone oxime esters
    An, Zhenyu
    Jiang, Yong
    Guan, Xin
    Yan, Rulong
    [J]. CHEMICAL COMMUNICATIONS, 2018, 54 (76) : 10738 - 10741
  • [3] FeCl3-Catalyzed synthesis of pyrrolo[1,2-a]-quinoxaline derivatives from 1-(2-aminophenyl)-pyrroles through annulation and cleavage of cyclic ethers
    An, Zhenyu
    Zhao, Lianbiao
    Wu, Mingzhong
    Ni, Jixiang
    Qi, Zhenjie
    Yu, Guiqin
    Yan, Rulong
    [J]. CHEMICAL COMMUNICATIONS, 2017, 53 (84) : 11572 - 11575
  • [4] Iridium-Catalyzed Hydrogen Transfer: Synthesis of Substituted Benzofurans, Benzothiophenes, and Indoles from Benzyl Alcohols
    Anxionnat, Bruno
    Pardo, Domingo Gomez
    Ricci, Gino
    Rossen, Kai
    Cossy, Janine
    [J]. ORGANIC LETTERS, 2013, 15 (15) : 3876 - 3879
  • [5] The Direct Synthesis of Imines, Benzimidazoles and Quinoxalines from Nitroarenes and Carbonyl Compounds by Selective Nitroarene Hydrogenation Employing a Reusable Iron Catalyst
    Baeumler, Christoph
    Kempe, Rhett
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (36) : 8989 - 8993
  • [6] Nickel-catalysed dehydrogenative coupling of aromatic diamines with alcohols: selective synthesis of substituted benzimidazoles and quinoxalines
    Bera, Atanu
    Sk, Motahar
    Singh, Khushboo
    Banerjee, Debasis
    [J]. CHEMICAL COMMUNICATIONS, 2019, 55 (42) : 5958 - 5961
  • [7] In Situ Generated Cobalt Catalyst for the Dehydrogenative Coupling of Alcohols and Amines into Imines
    Bottaro, Fabrizio
    Madsen, Robert
    [J]. CHEMCATCHEM, 2019, 11 (11) : 2707 - 2712
  • [8] Asymmetric Copper-Catalyzed Azide-Alkyne Cycloadditions
    Brittain, William D. G.
    Buckley, Benjamin R.
    Fossey, John S.
    [J]. ACS CATALYSIS, 2016, 6 (06): : 3629 - 3636
  • [9] Thiazoles, Their Benzofused Systems, and Thiazolidinone Derivatives: Versatile and Promising Tools to Combat Antibiotic Resistance
    Cascioferro, Stella
    Parrino, Barbara
    Carbone, Daniela
    Schillaci, Domenico
    Giovannetti, Elisa
    Cirrincione, Girolamo
    Diana, Patrizia
    [J]. JOURNAL OF MEDICINAL CHEMISTRY, 2020, 63 (15) : 7923 - 7956
  • [10] Cooperative iridium complex-catalyzed synthesis of quinoxalines, benzimidazoles and quinazolines in water
    Chakrabarti, Kaushik
    Maji, Milan
    Kundu, Sabuj
    [J]. GREEN CHEMISTRY, 2019, 21 (08) : 1999 - 2004