Cobalt-zinc nitride on nitrogen doped carbon black nanohybrids as a non-noble metal electrocatalyst for oxygen reduction reaction

被引：56
作者：
Yuan, Y. [1 ,2 ]
Yang, L. [1 ,2 ]
He, B. [1 ]
Pervaiz, E. [1 ,3 ]
Shao, Z. [1 ]
Yang, M. [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China
[3] Natl Univ Sci Technol NUST, Sch Chem & Mat Engn SCME, Islamabad 44000, Pakistan
来源：
NANOSCALE | 2017年 / 9卷 / 19期
基金：
中国国家自然科学基金;
关键词：
PERFORMANCE; PHTHALOCYANINE; CATALYSTS; GRAPHENE; SUPPORT; IRON;
D O I：
10.1039/c7nr02264f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bimetallic nitrides are now being considered as one of the emerging advanced functional materials due to their characteristic features and remarkable physicochemical properties. Herein, we report a new crystalline bimetallic nitride (Co3ZnN) that belongs to the cubic crystal phase, which was successfully synthesized through direct nitridation of metallic salts as precursors. Co3ZnN nanoparticles were then supported on nitrogen-doped XC-72 carbon black (N-CB), and this typical Co3ZnN/N-CB nanohybrid discovered can serve as an efficient non-noble metal electrocatalyst with a 4e(-) reaction pathway for ORR, and demonstrated excellent electrocatalytic performance with high activity and stability.
引用
收藏
页码：6259 / 6263
页数：5
相关论文
共 28 条
  • [1] A novel CoN electrocatalyst with high activity and stability toward oxygen reduction reaction
    An, Li
    Huang, Weifeng
    Zhang, Nanlin
    Chen, Xin
    Xia, Dingguo
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (01) : 62 - 65
  • [2] Mixed Close-Packed Cobalt Molybdenum Nitrides as Non-noble Metal Electrocatalysts for the Hydrogen Evolution Reaction
    Cao, Bingfei
    Veith, Gabriel M.
    Neuefeind, Joerg C.
    Adzic, Radoslav R.
    Khalifah, Peter G.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (51) : 19186 - 19192
  • [3] Cobalt Molybdenum Oxynitrides: Synthesis, Structural Characterization, and Catalytic Activity for the Oxygen Reduction Reaction
    Cao, Bingfei
    Veith, Gabriel M.
    Diaz, Rosa E.
    Liu, Jue
    Stach, Eric A.
    Adzic, Radoslav R.
    Khalifah, Peter G.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (41) : 10753 - 10757
  • [4] Nano-TaOxNy particles synthesized from oxy-tantalum phthalocyanine: how to prepare precursors to enhance the oxygen reduction reaction activity after ammonia pyrolysis?
    Chisaka, M.
    Ishihara, A.
    Uehara, N.
    Matsumoto, M.
    Imai, H.
    Ota, K.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (32) : 16414 - 16418
  • [5] Cui H. L. Bai, 2011, ACTA PHYS-CHIM SIN, P27
  • [6] Tungsten nitride nanocrystals on nitrogen-doped carbon black as efficient electrocatalysts for oxygen reduction reactions
    Dong, Youzhen
    Li, Jinghong
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (03) : 572 - 575
  • [7] Gopinath M. M. a. C. S., 2009, CHEM MATER, V21, P9
  • [8] Hydrothermal synthesis of vanadium nitride and modulation of its catalytic performance for oxygen reduction reaction
    Huang, Taizhong
    Mao, Shun
    Zhou, Guihua
    Wen, Zhenhai
    Huang, Xingkang
    Ci, Suqin
    Chen, Junhong
    [J]. NANOSCALE, 2014, 6 (16) : 9608 - 9613
  • [9] Recent advances in non-precious metal catalysis for oxygen-reduction reaction in polymer electrolyte fuel cells
    Jaouen, Frederic
    Proietti, Eric
    Lefevre, Michel
    Chenitz, Regis
    Dodelet, Jean-Pol
    Wu, Gang
    Chung, Hoon Taek
    Johnston, Christina Marie
    Zelenay, Piotr
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (01) : 114 - 130
  • [10] Reduction of the oxygen reduction reaction overpotential of nitrogen-doped graphene by designing it to a microspherical hollow shape
    Jiang, Zhong-Jie
    Jiang, Zhongqing
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (34) : 14071 - 14081
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