Single-Source Precursor for Tungsten Dichalcogenide Thin Films: Mo1-xWxS2 (0 ≤ x ≤ 1) Alloys by Aerosol-Assisted Chemical Vapor Deposition

被引：25
作者：
Tedstone, Aleksander A. [1 ]
Lewis, Edward A. [2 ]
Savjani, Nicky [1 ,3 ]
Zhong, Xiang Li [2 ]
Haigh, Sarah J. [2 ]
O'Brien, Paul [1 ,2 ]
Lewis, David J. [2 ]
机构：
[1] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England
[2] Univ Manchester, Sch Mat, Oxford Rd, Manchester M13 9PL, Lancs, England
[3] Nanoco Technol Ltd, 46 Grafton St, Manchester M13 9NT, Lancs, England
来源：
CHEMISTRY OF MATERIALS | 2017年 / 29卷 / 09期
基金：
英国工程与自然科学研究理事会;
关键词：
MOLYBDENUM-DISULFIDE; MONOLAYER MOS2; COMPLEXES; AACVD; NANOPARTICLES; CVD;
D O I：
10.1021/acs.chemmater.6b05271
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Researchers reported the alloying of MoS2 with W by AACVD using WS3 L2 and MoL4 molecular precursors to produce Mo1-XWXS2 polycrystalline thin films over the range 0 ≤ x ≤ 1. The synthesis of the novel air-stable single source precursor WS3 L2 was achieved by the reaction of [NH4]2 WS4 and sodium diethyldithiocarbamate in an acidic medium, to produce WS3 L2 as a dark green powder, accompanied by a small quantity of the tungsten dimer W2 S4 L4 , which was isolated and analyzed separately.
引用
收藏
页码：3858 / 3862
页数：5
相关论文
共 44 条
  • [1] Studies of molybdenum disulfide nanostructures prepared by AACVD using single-source precursors
    Adeogun, Adekunle
    Afzaal, Mohammad
    O'Brien, Paul
    [J]. CHEMICAL VAPOR DEPOSITION, 2006, 12 (10) : 597 - 599
  • [2] Chemical vapour deposition of rhenium disulfide and rhenium-doped molybdenum disulfide thin films using single-source precursors
    Al-Dulaimi, Naktal
    Lewis, David J.
    Zhong, Xiang Li
    Malik, M. Azad
    O'Brien, Paul
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2016, 4 (12) : 2312 - 2318
  • [3] ONE POT SYNTHESIS OF DINUCLEAR TUNGSTEN(V) COMPOUNDS CONTAINING [W2XY(MU-S)2]2+ (X=O, S/Y = O, S) CORES BY THERMALLY INDUCED INTERNAL ELECTRON-TRANSFER PROCESSES
    ANSARI, MA
    CHANDRASEKARAN, J
    SARKAR, S
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (06) : 2265 - 2267
  • [4] Chen YF, 2014, NANOSCALE, V6, P2833, DOI [10.1039/c3nr05630a, 10.1039/c3r05630a]
  • [5] Studies of the thermal decomposition of some diselenocarbamato complexes of cadmium or zinc: molecular design for the deposition of MSe films by CVD
    Chunggaze, M
    Malik, MA
    O'Brien, P
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (10) : 2433 - 2437
  • [6] Raman study of 2H-Mo1-xWxS2 layered mixed crystals
    Dumcenco, D. O.
    Chen, K. Y.
    Wang, Y. P.
    Huang, Y. S.
    Tiong, K. K.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 506 (02) : 940 - 943
  • [7] DIALKYLDITHIOCARBAMATE COMPLEXES OF TUNGSTEN(VI) - SYNTHESIS, PROPERTIES AND STRUCTURE OF THIODICHLOROBIS(DIMETHYLDITHIOCARBAMATO)TUNGSTEN(VI)
    FEDIN, VP
    MIRONOV, YV
    VIROVETS, AV
    PODBEREZSKAYA, NV
    FEDOROV, VY
    SEMYANNIKOV, PP
    [J]. POLYHEDRON, 1992, 11 (02) : 279 - 284
  • [8] Transition Metal Chalcogenides: Ultrathin Inorganic Materials with Tunable Electronic Properties
    Heine, Thomas
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (01) : 65 - 72
  • [9] Biornimetic hydrogen evolution:: MoS2 nanoparticles as catalyst for hydrogen evolution
    Hinnemann, B
    Moses, PG
    Bonde, J
    Jorgensen, KP
    Nielsen, JH
    Horch, S
    Chorkendorff, I
    Norskov, JK
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (15) : 5308 - 5309
  • [10] Scalable high-mobility MoS2 thin films fabricated by an atmospheric pressure chemical vapor deposition process at ambient temperature
    Huang, Chung-Che
    Al-Saab, Feras
    Wang, Yudong
    Ou, Jun-Yu
    Walker, John C.
    Wang, Shuncai
    Gholipour, Behrad
    Simpson, Robert E.
    Hewak, Daniel W.
    [J]. NANOSCALE, 2014, 6 (21) : 12792 - 12797
12345