A numerical model of crevice corrosion for passive and active metals

被引：80

作者：

Walton, JC

Cragnolino, G

Kalandros, SK

机构：

[1] Ctr. Nucl. Waste Regulatory Analyses, Southwest Research Institute, San Antonio

[2] Department of Civil Engineering, University of Texas at El Paso, El Paso

[3] Department of Electrical Engineering, University of Wisconsin, Madison, WI

来源：

CORROSION SCIENCE | 1996年 / 38卷 / 01期

关键词：

steel; stainless steel; polarization; crevice corrosion; pitting corrosion;

D O I：

10.1016/0010-938X(96)00107-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A transient mathematical and numerical model for crevice corrosion is presented. The model is general in format and applicable to a variety of metallic and electrolyte systems. It allows consideration of electrode kinetics including both cathodic and anodic reactions with an active/passive transition. Chemical reactions in solution are generalized to facilitate simulation of a variety of electrolytes. The model is applied to experimental data on crevice corrosion initiation in stainless steel and to experiments on active crevice corrosion of iron.

引用

页码：1 / 18

页数：18

共 19 条

[1] THE DETERMINATION OF PH, POTENTIAL AND CHLORIDE CONCENTRATION IN CORRODING CREVICES ON 304-STAINLESS STEEL AND 7475-ALUMINUM ALLOY [J].