Rhodium dithiocarbamate compounds as metalloligands: A controlled way for the construction of binuclear complexes

被引：23

作者：

Elduque, A

Finestra, C

Lopez, JA

Lahoz, FJ

Merchan, F

Oro, LA ^{[1
]}

Pinillos, MT

机构：

[1] Univ Zaragoza, Consejo Super Invest Cient, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain

[2] Univ Zaragoza, Consejo Super Invest Cient, Inst Ciencia Mat Aragon, Dept Quim Organ, E-50009 Zaragoza, Spain

[3] Univ La Rioja, Dept Quim Inorgan, Logrono 26001, Spain

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 04期

关键词：

D O I：

10.1021/ic971053t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of N-methyl,N-phenyl-dithiocarbamate mononuclear rhodium(I) complexes is described, and their capability to act as metalloligands for the controlled construction of binuclear dithiocarbamate-bridged species of general formula [Rh-2{mu-S2CN(Me)(Ph)}(COD)L-2]BF4 is investigated. Although in the mononuclear complexes the dithiocarbamate group coordinates as an S,S'-chelate ligand, in the reported binuclear compounds this ligand shows a novel bridging eta(2),eta(2)(S,S') coordination mode. EHT calculations based on these binuclear complexes indicate the intermetallic symmetric mu-eta,(2) eta(2)(S,S') coordination to be the most stable situation.

引用

页码：824 / +

页数：7

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