Preparation of zirconium oxide with polyaniline nanocatalyst for the decomposition of pharmaceutical industrial wastewater

被引:24
作者
Vijayalakshmi, S. [1 ,2 ]
Kumar, E. [3 ]
Venkatesh, P. Sundara [2 ]
Raja, A. [4 ]
机构
[1] Bharathiyar Univ, Res & Dev Ctr, Coimbatore 626210, Tamil Nadu, India
[2] Sri S Ramasamy Naidu Mem Coll, Dept Phys, Sattur 626203, Tamil Nadu, India
[3] Tamilnadu Open Univ, Sch Sci, Chennai 600015, Tamil Nadu, India
[4] Deemed Be Univ, Dept Phys, Multifunct Mat Res Lab, Kalasalingam Acad Res & Educ, Krishnankoil 626126, Tamil Nadu, India
关键词
Ciprofloxacin; Photodecomposition; SEM; UV-Visible; PHOTOCATALYTIC DEGRADATION; NANOCOMPOSITES; CIPROFLOXACIN; ANTIBIOTICS; COMPOSITES; REMOVAL;
D O I
10.1007/s11581-019-03323-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The decomposition of ciprofloxacin antibiotic from pharmaceutical wastewater treatment was investigated by PANI/ZrO2 nanocomposite. The sample was characterized by X-ray diffraction (XRD) Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and UV-Vis absorption spectroscopy. The phase identification of pure ZrO2 and PANI/ZrO2 nanocomposite was confirmed by XRD analysis, and functional analysis was confirmed by FT-IR spectroscopy. The formation of micro and nanostructure was confirmed by TEM analysis. The photodecomposition of PANI/ZrO2 composite was investigated for ciprofloxacin under UV light irradiation. Almost complete decomposition of ciprofloxacin is occurs at 120 min. Graphical abstract
引用
收藏
页码:1507 / 1513
页数:7
相关论文
共 27 条
[1]   Efficient Remediation of an Aquatic Environment Contaminated by Cr(VI) and 2,4-Dinitrophenol by XG-g-Polyaniline@ZnO Nanocomposite [J].
Ahmad, Rais ;
Hasan, Imran .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2017, 62 (05) :1594-1607
[2]  
Bisht B., 2017, CURR SMART MAT, V2, P130, DOI DOI 10.2174/2405465802666170707163408
[3]   Properties of Zirconia/Polyaniline hybrid nanocomposites and their application as photocatalysts for degradation of model pollutants [J].
Carevi, M. V. ;
Abazovi, N. D. ;
Mitric, M. N. ;
Ciric-Marjanovic, G. ;
Mojovic, M. D. ;
Ahrenkiel, S. P. ;
Comor, M. I. .
MATERIALS CHEMISTRY AND PHYSICS, 2018, 205 :130-137
[4]   Recent advances in polyaniline composites with metals, metalloids and nonmetals [J].
Ciric-Marjanovic, Gordana .
SYNTHETIC METALS, 2013, 170 :31-56
[5]   Chemical polymerization, characterization and electrochemical studies of PANI/ZnO doped with hydrochloric acid and/or zinc chloride: Differences between the synthesized nanocomposites [J].
Daikh, S. ;
Zeggai, F. Z. ;
Bellil, A. ;
Benyoucef, A. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2018, 121 :78-84
[6]   Fabrication of TiO2/CoMoO4/PANI nanocomposites with enhanced photocatalytic performances for removal of organic and inorganic pollutants under visible light [J].
Feizpoor, Solmaz ;
Habibi-Yangjeh, Aziz ;
Yubuta, Kunio ;
Vadivel, S. .
MATERIALS CHEMISTRY AND PHYSICS, 2019, 224 :10-21
[7]   A novel 3D-structured flower-like bismuth tungstate/mag-graphene nanoplates composite with excellent visible-light photocatalytic activity for ciprofloxacin degradation [J].
Hou, Xiaohong ;
Liu, Jingjing ;
Guo, Wei ;
Li, Sijia ;
Guo, Yating ;
Shi, Yue ;
Zhang, Conglu .
CATALYSIS COMMUNICATIONS, 2019, 121 :27-31
[8]   Occurrence, partition and removal of pharmaceuticals in sewage water and sludge during wastewater treatment [J].
Jelic, Aleksandra ;
Gros, Meritxell ;
Ginebreda, Antoni ;
Cespedes-Sanchez, Raquel ;
Ventura, Francesc ;
Petrovic, Mira ;
Barcelo, Damia .
WATER RESEARCH, 2011, 45 (03) :1165-1176
[9]   Recent Developments about Conductive Polymer Based Composite Photocatalysts [J].
Lee, Sher Ling ;
Chang, Chi-Jung .
POLYMERS, 2019, 11 (02)
[10]   Recent advancements of polyaniline-based nanocomposites for supercapacitors [J].
Liu, Panbo ;
Yan, Jing ;
Guang, Zhaoxu ;
Huang, Ying ;
Li, Xifei ;
Huang, Wenhuan .
JOURNAL OF POWER SOURCES, 2019, 424 :108-130