Facile synthesis of an organically-derivatized hexavanadate containing the remote amino group, TBA2[V6O13{(OCH2)3CNH2}2]

被引：23

作者：

Bayaguud, Aruuhan ^{[1
]}

Chen, Kun ^{[1
]}

Wei, Yongge ^{[1
,2
]}

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Minist Educ, Beijing 100084, Peoples R China

[2] Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China

来源：

CRYSTENGCOMM | 2016年 / 18卷 / 22期

基金：

高等学校博士学科点专项科研基金; 中国国家自然科学基金;

关键词：

STRUCTURAL-CHARACTERIZATION; O-2-BASED OXIDATIONS; HYBRID; CLUSTERS; COMPLEXES; CORE;

D O I：

10.1039/c5ce02534f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An effective synthetic strategy for the amino-containing organic derivative of hexavanadate, TBA(2)[V6O13{(OCH2)(3)CNH2}(2)], is presented. By using this method, the yield is increased extremely and crystals of the intermediate and cation-exchanged products are both obtained and structurally characterized via single-crystal X-ray diffraction, IR and H-1-NMR.

引用

页码：4042 / 4045

页数：4

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