Photophysical and photochemical properties of non-peripheral butoxy-substituted phthalocyanines with absorption in NIR range

被引：16
作者：
Safonova, Evgeniya A. [1 ]
Meshkov, Ivan N. [1 ]
Polovkova, Marina A. [1 ]
Volostnykh, Marina V. [1 ]
Tsivadze, Asian Yu. [1 ,2 ]
Gorbunova, Yulia G. [1 ,2 ]
机构：
[1] Russian Acad Sci, AN Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia
[2] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2018年 / 28卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
SINGLET OXYGEN; PROTONATION; ZINC; RED; PHOTOPROPERTIES; DERIVATIVES; OXIDATION; CATALYSTS; DYES;
D O I：
10.1016/j.mencom.2018.05.015
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The optical properties of non-peripheral octabutoxyphthalocyanine (PcH2) and the corresponding complexes PcM (M = Mg-II, Zn-II, Gam(III), In-III) in DMSO solutions were examined. Singlet oxygen generation quantum yields increase in the sequence PcH2 < PcMg < PcInCl < PcGaCI < PcZn and vary from 4 up to 36%; protonation of PcM quenches both fluorescence and singlet oxygen generation. The photocatalytic activity of PcGaCl in the photooxidation of 1,5-dihydroxynaphthalene was revealed.
引用
收藏
页码：275 / 277
页数：3
相关论文
共 33 条
  • [1] BARKANOVA SV, 1989, ZH OBSHCH KHIM+, V59, P1433
  • [2] Photodegradation of 1,5-dihydroxynaphthalene catalyzed by meso-tetra (4-sulfonatophenyl)porphyrin in aerated aqueous solution
    Cai, Jin-Hua
    Huang, Jin-Wang
    Zhao, Ping
    Zhou, Ying-Hua
    Yu, Han-Cheng
    Ji, Liang-Nian
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 292 (1-2) : 49 - 53
  • [3] Photocatalytic oxidation of 1-hexene using GaPc and InPc octasubstituted derivatives
    Chauke, Vongani
    Nyokong, Tebello
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 289 (1-2) : 9 - 13
  • [4] OCTA-ALKOXY PHTHALOCYANINE AND NAPHTHALOCYANINE DERIVATIVES - DYES WITH Q-BAND ABSORPTION IN THE FAR RED OR NEAR-INFRARED
    COOK, MJ
    DUNN, AJ
    HOWE, SD
    THOMSON, AJ
    HARRISON, KJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (08): : 2453 - 2458
  • [5] Engineering of relevant photodynamic processes through structural modifications of metallotetrapyrrolic photosensitizers
    Dabrowski, Janusz M.
    Pucelik, Barbara
    Regiel-Futyra, Anna
    Brindell, Malgorzata
    Mazuryk, Olga
    Kyziol, Agnieszka
    Stochel, Grayna
    Macyk, Wojciech
    Arnaut, Luis G.
    [J]. COORDINATION CHEMISTRY REVIEWS, 2016, 325 : 67 - 101
  • [6] DERKACHEVA VM, 1981, ZH OBSHCH KHIM+, V51, P2319
  • [7] Synthesis, X-ray crystal structure, UV/Visible linear and nonlinear (optical limiting) spectral properties of symmetrical and unsymmetrical porphyrazines with annulated 1,2,5-thiadiazole and 1,4-diamyloxybenzene moieties
    Donzello, MP
    Ercolani, C
    Gaberkorn, AA
    Kudrik, EV
    Meneghetti, M
    Marcolongo, G
    Rizzoli, C
    Stuzhin, PA
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (17) : 4009 - 4024
  • [8] Synthesis of chlorins, bacteriochlorins and their tetraaza analogues
    Dudkin, Semyon V.
    Makarova, Elena A.
    Lukyanets, Evgeny A.
    [J]. RUSSIAN CHEMICAL REVIEWS, 2016, 85 (07) : 700 - 730
  • [9] PHOTOPROPERTIES OF ALKOXY-SUBSTITUTED PHTHALOCYANINES WITH DEEP-RED OPTICAL ABSORBANCE
    FORD, WE
    RIHTER, BD
    KENNEY, ME
    RODGERS, MAJ
    [J]. PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1989, 50 (03) : 277 - 282
  • [10] Excited states and electronic spectra of annulated dinuclear free-base phthalocyanines: A theoretical study on near-infrared-absorbing dyes
    Fukuda, Ryoichi
    Ehara, Masahiro
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2012, 136 (11)
1234