Trifluoromethanesulfanylamides as Easy-to-Handle Equivalents of the Trifluoromethanesulfanyl Cation (CF3S+): Reaction with Alkenes and Alkynes

被引：195

作者：

Ferry, Aurelien ^{[1
]}

Billard, Thierry ^{[1
]}

Langlois, Bernard. R. ^{[1
]}

Bacque, Eric ^{[2
]}

机构：

[1] Univ Lyon 1, Lab SERCOF, ICBMS, CNRS,UMR 5246, F-69622 Villeurbanne, France

[2] Sanofi Aventis SA, F-94403 Vitry Sur Seine, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 45期

关键词：

alkenes; alkynes; electrophilic addition; fluorine; trifluoromethanesulfanylamides; TRIFLUORIDE-PROMOTED REACTION; FREE-RADICAL ADDITION; TRIFLUOROMETHYLATING AGENTS; CONVENIENT SYNTHESIS; FLUORINE CHEMISTRY; ARYL; SULFIDES; DISULFIDES; CHLORIDE; HALIDES;

D O I：

10.1002/anie.200903387

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Making introductions: The CF3S unit can be added in an electrophilic fashion to alkenes and alkynes in reactions with trifluoromethanesulfanylamide reagents (see scheme; Ts = toluene-4-sulfonyl). The products obtained may be of interest, for example, in pharmaceutical chemistry and materials science. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8551 / 8555

页数：5

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