Synthesis of 5-hydroxymethyl furfural from cellulose via a two-step process in polar aprotic solvent

被引：28

作者：

Fan, Guozhi ^{[1
]}

Wang, Yuexin ^{[1
]}

Hu, Zongxiao ^{[1
]}

Yan, Juntao ^{[1
]}

Li, Jianfen ^{[1
]}

Song, Guangsen ^{[1
]}

机构：

[1] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Hubei, Peoples R China

来源：

CARBOHYDRATE POLYMERS | 2018年 / 200卷

关键词：

Cellulose; 5-Hydroxymethyl furfural; Glucose; Phosphotungstic acid; Two-step process; ONE-POT CELLULOSE; IONIC LIQUIDS; SELECTIVE DEHYDRATION; CATALYTIC CONVERSION; GLUCOSE; ACID; BIOMASS; HYDROLYSIS; ZEOLITE; DEPOLYMERIZATION;

D O I：

10.1016/j.carbpol.2018.08.043

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The synthesis of 5-hydroxymethyl furfural (HMF) from cellulose via a two-step process was investigated. To optimize reaction conditions, the separate conversion of cellulose and glucose was first performed in tetrahydrofuran (THF) and N, N-dimethylformamide (DMF) via a one-step process using hosphotungstic acid (PHA) as catalyst. The direct conversion of cellulose to HMF was then performed via the two-step process. The first step and the second step were carried out in THF and the mixture solvent composed of THF/DMF, respectively. Cellulose was converted to HMF and glucose in the first step in THF. Both of cellulose and the as-formed glucose were then converted to HMF in the second step. The conversion of cellulose to HMF and glucose were significantly improved by the two-step process, and the total yield of HMF and glucose was elevated from 52.1 to 97.0%. A possible mechanism for the formation of HMF from cellulose via the two-step process was also proposed.

引用

页码：529 / 535

页数：7

共 51 条

[1]

Abou-Yousef H, 2014, J IND ENG CHEM, V20, P1952

[2]

Abou-Yousef Hussein, 2013, [燃料化学学报, Journal of Fuel Chemistry and Technology], V41, P214

[3] Characterizing ionic liquids on the basis of multiple solvation interactions [J].

Anderson, JL ;

Ding, J ;

Welton, T ;

Armstrong, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) :14247-14254

[4]

[Anonymous], 2009, APPL CATAL A, DOI DOI 10.1016/J.APCATA.2009.04.002

[5] High yield conversion of cellulosic biomass into 5-hydroxymethylfurfural and a study of the reaction kinetics of cellulose to HMF conversion in a biphasic system [J].

Atanda, Luqman ;

Konarova, Muxina ;

Ma, Qing ;

Mukundan, Swathi ;

Shrotri, Abhijit ;

Beltramini, Jorge .

CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (16) :6257-6266

[6] Recycle and Extraction: Cornerstones for an Efficient Conversion of Cellulose into 5-Hydroxymethylfurfural in Ionic Liquids [J].

Chiappe, Cinzia ;

Douton, Maria J. Rodriguez ;

Mezzetta, Andrea ;

Pomelli, Christian S. ;

Assanelli, Giulio ;

de Angelis, Alberto R. .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (06) :5529-5536

[7] A kinetic study on microwave-assisted conversion of cellulose and lignocellulosic waste into hydroxymethylfurfural/furfural [J].

da Silva Lacerda, Viviane ;

Benito Lopez-Sotelo, Juan ;

Correa-Guimaraes, Adriana ;

Hernandez-Navarro, Salvador ;

Sanchez-Bascones, Mercedes ;

Navas-Gracia, Luis M. ;

Martin-Ramos, Pablo ;

Perez-Lebena, Eduardo ;

Martin-Gil, Jesus .

BIORESOURCE TECHNOLOGY, 2015, 180 :88-96

[8] 5-Hydroxymethylfurfural production from sugars and cellulose in acid- and base-catalyzed conditions under hot compressed water [J].

Daorattanachai, Pornlada ;

Namuangruk, Supawadee ;

Viriya-empikul, Nawin ;

Laosiripojana, Navadol ;

Faungnawakij, Kajornsak .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2012, 18 (06) :1893-1901

[9] Conversion of fructose, glucose, and cellulose to 5-hydroxymethylfurfural by alkaline earth phosphate catalysts in hot compressed water [J].

Daorattanachai, Pornlada ;

Khemthong, Pongtanawat ;

Viriya-empikul, Nawin ;

Laosiripojana, Navadol ;

Faungnawakij, Kajornsak .

CARBOHYDRATE RESEARCH, 2012, 363 :58-61

[10]

de Carvalho E. G., 2018, BIOMASS CONVERS BIOR, P1

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