Equation of state of bcc-Mo by static volume compression to 410 GPa

被引:22
作者
Akahama, Yuichi [1 ]
Hirao, Naohisa [2 ]
Ohishi, Yasuo [2 ]
Singh, Anil K. [3 ]
机构
[1] Univ Hyogo, Grad Sch Mat Sci, Kamigori, Hyogo 6781297, Japan
[2] Japan Synchrotron Radiat Res Inst JASRI, Mikazuki, Hyogo 6795198, Japan
[3] Natl Aerosp Labs, Div Mat Sci, Bangalore 560017, Karnataka, India
基金
日本学术振兴会;
关键词
X-RAY-DIFFRACTION; STRUCTURAL PHASE-TRANSITIONS; SHOCK COMPRESSION; LATTICE STRAINS; PRESSURE; MOLYBDENUM; GOLD; CR; VELOCITIES; PLATINUM;
D O I
10.1063/1.4903940
中图分类号
O59 [应用物理学];
学科分类号
摘要
Unit cell volumes of Mo and Pt have been measured simultaneously to approximate to 400GPa by x-ray powder diffraction using a diamond anvil cell and synchrotron radiation source. The body-centered cubic (bcc) phase of Mo was found to be stable up to 410 GPa. The equation of state (EOS) of bcc-Mo was determined on the basis of Pt pressure scale. A fit of Vinet EOS to the volume compression data gave K-0 = 262.3(4.6) GPa, K-0' = 4.55(16) with one atmosphere atomic volume V-0 = 31.155(24) A(3). The EOS was in good agreement with the previous ultrasonic data within pressure difference of 2.5%-3.3% in the multimegabar range, though the EOS of Mo proposed from a shock compression experiment gave lower pressure by 7.2%-11.3% than the present EOS. The agreement would suggest that the Pt pressure scale provides an accurate pressure value in an ultra-high pressure range. (C) 2014 AIP Publishing LLC.
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页数:5
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