Gasification of Wood and Torrefied Wood with Air, Oxygen, and Steam in a Fixed-Bed Pilot Plant

被引:42
作者
Cerone, N. [1 ,2 ]
Zimbardi, F. [1 ]
Villone, A. [1 ]
Strjiugas, N. [1 ]
Kiyikci, E. G. [1 ]
机构
[1] Italian Natl Agcy New Technol Energy & Sustainabl, Energy Technol Dept, Res Ctr Trisaia, I-75026 Rotondella, Italy
[2] Univ Naples Federico II, Dept Chem Engn Mat & Ind Prod, Piazzale Tecchio 80, I-80125 Naples, Italy
关键词
BIOMASS GASIFICATION; SYNGAS PRODUCTION; TORREFACTION; COAL; GRINDABILITY; COMBUSTION; ACTIVATION; REACTIVITY; IMPACT; ENERGY;
D O I
10.1021/acs.energyfuels.6b00126
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this work, the efficiency of the updraft gasification of different biomass was analyzed using a 20 kg/h pilot facility. Eucalyptus wood chips, torrefied Eucalyptus wood chips, and torrefied Spruce chips were investigated. Absolute air, mixes of air with steam, and mixes of pure oxygen with steam were used as gasification media. The direct comparison between the parental and torrefied biomass emphasizes the positive effect of this pretreatment on syngas properties and plant performances. Typically, the use of torrefied feedstock resulted in a reduction to about 1/5 of the tar load in the syngas and in 44% increment of the thermal power of the plant when compared to the performances obtained with the parental wood. The introduction of steam as co-gasifying stream was effective to avoid hot spots inside the reactive bed and to stabilize the process. Moreover, the use of steam positively affected the molar ratio of H-2/CO that reached the value of 1.17 with the H-2 concentration in the syngas of 39 vol %. The cold gas efficiency was 0.85 with torrefied biomass and pure oxygen with steam (0.82 when taking into account the energy for steam production), whereas the use of parental wood in similar conditions gave a value of 0.67 (net of 0.65). The treatment capacity of the plant was directly proportional to the reactivity of the feedstock as assessed by thermogravimetric analysis when the feed was reported as volumetric flow.
引用
收藏
页码:4034 / 4043
页数:10
相关论文
共 33 条
[1]   Influence of torrefaction on the grindability and reactivity of woody biomass [J].
Arias, B. ;
Pevida, C. ;
Fermoso, J. ;
Plaza, M. G. ;
Rubiera, F. ;
Pis, J. J. .
FUEL PROCESSING TECHNOLOGY, 2008, 89 (02) :169-175
[2]   High temperature steam gasification of woody biomass - A combined experimental and mathematical modeling approach [J].
Balu, Elango ;
Lee, Uisung ;
Chung, J. N. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (41) :14104-14115
[3]   Chemical composition changes in eucalyptus and pinus woods submitted to heat treatment [J].
Brito, J. O. ;
Silva, F. G. ;
Leao, M. M. ;
Almeida, G. .
BIORESOURCE TECHNOLOGY, 2008, 99 (18) :8545-8548
[4]   Updraft Gasification at Pilot Scale of Hydrolytic Lignin Residue [J].
Cerone, N. ;
Zimbardi, F. ;
Contuzzi, L. ;
Alvino, E. ;
Carnevale, M. O. ;
Valerio, V. .
ENERGY & FUELS, 2014, 28 (06) :3948-3956
[5]   Maximizing biofuel production in a thermochemical biorefinery by adding electrolytic hydrogen and by integrating torrefaction with entrained flow gasification [J].
Clausen, Lasse R. .
ENERGY, 2015, 85 :94-104
[6]   Volatile yields and solid grindability after torrefaction of various biomass types [J].
Commandre, J. M. ;
Leboeuf, A. .
ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, 2015, 34 (04) :1180-1186
[7]   Impact of torrefaction on syngas production from wood [J].
Couhert, C. ;
Salvador, S. ;
Commandre, J-M. .
FUEL, 2009, 88 (11) :2286-2290
[9]   Biomass gasification: Influence of torrefaction on syngas production and tar formation [J].
Dudynski, Marek ;
van Dyk, Johan C. ;
Kwiatkowski, Kamil ;
Sosnowska, Marta .
FUEL PROCESSING TECHNOLOGY, 2015, 131 :203-212
[10]   ESTIMATING THERMODYNAMIC PROPERTIES OF COAL, CHAR, TAR AND ASH [J].
EISERMANN, W ;
JOHNSON, P ;
CONGER, WL .
FUEL PROCESSING TECHNOLOGY, 1980, 3 (01) :39-53