Engineered Nitrogen-Decorated Carbon Networks for the Metal-Free Catalytic Isomerization of Glucose to Fructose

被引：18

作者：

Chen, Season S. ^{[1
,2
,3
]}

Carraher, Jack M. ^{[1
,2
]}

Tuci, Giulia ^{[4
]}

Rossin, Andrea ^{[4
]}

Raman, Caleb A. ^{[1
,2
]}

Luconi, Lapo ^{[4
]}

Tsang, Daniel C. W. ^{[3
]}

Giambastiani, Giuliano ^{[4
,5
,6
]}

Tessonnier, Jean-Philippe ^{[1
,2
]}

机构：

[1] Iowa State Univ, Dept Chem & Biol Engn, Ames, IA 50011 USA

[2] Ctr Biorenewable Chem CBiRC, Ames, IA 50011 USA

[3] Hong Kong Polytech Univ, Dept Civil & Environm Engn, Kowloon, Hong Kong, Peoples R China

[4] CNR, Inst Chem OrganoMetall Cpds ICCOM CNR, Via Madonna Piano 10, I-50019 Florence, Italy

[5] Univ Strasbourg, UMR 7515, Inst Chem & Proc Energy Environm & Hlth ICPEES, ECPM,CNRS, 25 Rue Becquerel, F-67087 Strasbourg 02, France

[6] Kazan Fed Univ, Kazan 420008, Russia

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2019年 / 7卷 / 20期

基金：

美国国家科学基金会;

关键词：

Glucose-to-fructose isomerization; Metal-free heterogeneous catalysis; N-Decorated nanocarbons; Chemical functionalization; Functional group synergy; CARBOCATALYSIS; REACTIVITY; CONVERSION; NANOTUBES; BIOMASS; SUGARS;

D O I：

10.1021/acssuschemeng.9b04067

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bronsted bases have recently been reported to catalyze the glucose isomerization to fructose. This contribution describes the rational bottom-up approach to the design and synthesis of heterogeneous systems based on a C-60 platform surface engineered with catalytically active amino functionalities tethered to carbon nanomaterials within variable (polar/apolar) chemical microenvironments. We demonstrate how carbocatalysts performance for the glucose-to-fructose isomerization may improve depending on amines' neighboring functional groups and their chemical interplay at the C-nanocarrier surface.

引用

页码：16959 / 16963

页数：9

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