Pore characteristics in one-part mix geopolymers foamed by H2O2: The impact of mix design

被引:158
作者
Hajimohammadi, Ailar [1 ]
Ngo, Tuan [1 ]
Mendis, Priyan [1 ]
Nguyen, Tuan [1 ]
Kashani, Alireza [1 ]
van Deventer, Jannie S. J. [2 ,3 ]
机构
[1] Univ Melbourne, Dept Infrastruct Engn, Melbourne, Vic 3010, Australia
[2] Univ Melbourne, Dept Chem & Biomol Engn, Melbourne, Vic 3010, Australia
[3] Zeobond Pty Ltd, POB 23450, Docklands, Vic 8012, Australia
基金
澳大利亚研究理事会;
关键词
Geopolymer foam; Pore size distribution; H2O2; Non-destructive testing; Finite element analysis; Mesoscale modelling; BOUNDARY-CONDITIONS; HYDROGEN-PEROXIDE; ASH; CONCRETE; SILICA; ABSORPTION; AGENT; PERFORMANCE; STRENGTH; BEHAVIOR;
D O I
10.1016/j.matdes.2017.05.084
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In geopolymers foamed by H2O2, it is important to consider the impact of mix design on both geopolymerisation reaction and the H2O2 foaming reaction to control the porosity of the geopolymer foam matrix. In this paper, the effect of mix design on both reactions is discussed and correlated with the properties of the resulting geopolymer foams. It is found that when the mix design provides a chemically stable environment for the foaming reaction and simultaneously facilitates rapid setting of the binders, it results in homogeneously distributed fine pores within the matrix. The homogeneity of pore distribution is determined by a non-destructive test and correlated with the thermal conductivity results. It is suggested that for better thermal insulating properties, geopolymer foams are preferably poured and cured parallel to the heat flow direction. The size distribution of pores is shown to be a critical parameter in determining the strength of foams, and the mesoscale-based finite element analysis is performed to create a predictive tool for correlating the pore size distribution of geopolymer foams with their mechanical properties. [GRAPHICS] .
引用
收藏
页码:381 / 391
页数:11
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