Complexes of silanethiolate ligands: Synthesis, structure, properties and application

被引：3

作者：

Pladzyk, Agnieszka ^{[1
]}

Kowalkowska-Zedler, Daria ^{[1
]}

Ciborska, Anna ^{[1
]}

Schnepf, Andreas ^{[2
]}

Dolega, Anna ^{[1
]}

机构：

[1] Gdansk Univ Technol, Fac Chem, Dept Inorgan Chem, Narutowicza Str 11-12, Gdansk, Poland

[2] Univ Tubingen, Inst Inorgan Chem, Morgenstelle 18, D-72076 Tubingen, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 2021年 / 437卷

关键词：

Silanethiolate ligand; Metal ions; Synthetic methods; Molecular structure; Reactivity; SILICON-SULFUR-COMPOUNDS; TRI-TERT-BUTOXYSILANETHIOLATE; CUBANE-TYPE CLUSTERS; BOND COVALENT RADII; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; ACTIVE-SITE; X-RAY; ALCOHOL-DEHYDROGENASE; THIOLATE LIGANDS;

D O I：

10.1016/j.ccr.2020.213761

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The purposeful syntheses of silanethiolate complexes started approximately in the mid-eighties of the 20th century but no summary of the synthetic efforts has been reported till now. The synthetic methods and the resulting complexes have some common features, which are emphasized throughout the review. Thereby specific difficulties during synthesis are outlined and the structures, properties and possible applications of the resulting complexes are presented. All groups of metals of the periodic table are included and associated with potential applications regarding the specific properties of the silicon-sulfur bond and the attached metals. (C) 2020 The Authors. Published by Elsevier B.V.

引用

页数：73

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