Thermodynamic and experimental study of chemical bath deposition of Zn(S,O,OH) buffer layers in basic aqueous ammonia solutions.: Cell results with electrodeposited CuIn(S,Se)2 absorbers

被引：86
作者：
Hubert, C.
Naghavi, N.
Canava, B.
Etcheberry, A.
Lincot, D.
机构：
[1] ENSCP, CNRS, UMR 7174, EDF,IRDEP, F-78401 Chatou, France
[2] Univ Versailles, Inst Lavoisier, UMR 8180, F-78035 Versailles, France
来源：
THIN SOLID FILMS | 2007年 / 515卷 / 15期
关键词：
zinc sulphide; Chemical Bath Deposition; thermodynamic; solar cells; CuInSe2; CuInS2;
D O I：
10.1016/j.tsf.2006.12.139
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
This paper presents a thermodynamic study of Chemical Bath Deposition (CBD) of zinc sulphide based films in aqueous ammonia solutions. The aim is a better understanding of ammonia and temperature effects on the deposition conditions and films composition. The formation of solid phases has been predicted by means of the precipitation conditions of ZnO, Zn(OH)(2) and ZnS as a function of temperature between 298 and 333 K. Films have been deposited according to calculated diagrams and preliminary results on solar cells based on electrodeposited CuIn(S,Se)(2) layers have been demonstrated. Composition and thickness of the films have been extracted to link the theoretical study with experiments. (C) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：6032 / 6035
页数：4
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