Characterization of agriculture wastes based activated carbon for removal of hydrogen sulfide from petroleum refinery waste water

被引:28
作者
Habeeb, Omar Abed [1 ,2 ]
Kanthasamy, Ramesh [2 ]
Saber, Shihab Ezzuldin M. [1 ,2 ]
Olalere, Olusegun Abayomi [2 ]
机构
[1] North Refineries Co, Minist Oil Iraq, Baiji, Salahaldeen, Iraq
[2] Univ Malaysia Pahang, Fac Chem Engn & Nat Resources Engn, Gambang 26300, Pahang, Malaysia
关键词
Hydrogen sulfide; Adsorption; Characterization; Activated carbon; Waste water treatment; ADSORBENTS; H2S;
D O I
10.1016/j.matpr.2019.09.194
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Hydrogen sulfide (H2S) (aq) is one of the most toxic pollutants in petroleum refinery waste water. It is very harmful to human health and causes environmental and economic problems. The removal of H2S (aq) from a simulated petroleum refinery waste water using activated carbons produced from agricultural by-product such as, coconut shell (CNS), palm kernel shell (PKS), and wood sawdust (WSD) were investigated. The activated carbons obtained from the CNS, PKS, and WSD were chemically activated using KOH. The prepared ACs was characterized using SEM/EDX, FTIR, BET, and TGA. Comparative studies between all the three adsorbents for the removal of H2S (aq) from the simulated waste water were carried out. The adsorption studies revealed that modified PKS-based activated carbon (ACPKS) has shown best performance for the removal of H2S (aq). It can be concluded that ACPKS has an effective adsorbent for the removal of H2S (aq) from simulated waste water. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:588 / 594
页数:7
相关论文
共 25 条
[1]  
Abechi S. E., 2013, Research Journal of Chemical Sciences, V3, P54
[2]   Microfluidic cold stripping of H2S from crude oil in low temperature and natural gas consumption [J].
Almasvandi, Mohammad Hassan ;
Rahimi, Masoud ;
Tagheie, Yaghoub .
JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING, 2016, 34 :499-508
[3]   Thermal regeneration of a spent activated carbon previously used as hydrogen sulfide adsorbent [J].
Bagreev, A ;
Rahman, H ;
Bandosz, TJ .
CARBON, 2001, 39 (09) :1319-1326
[4]   On the adsorption/oxidation of hydrogen sulfide on activated carbons at ambient temperatures [J].
Bandosz, TJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 246 (01) :1-20
[5]   Hydrogen sulphide removal from the effluents of a phosphoric acid production unit by absorption into chlorinated seawater under alkaline conditions [J].
Boumnijel, Ibtissem ;
Ben Amor, Hedi ;
Chekir, Hassen ;
Hajji, Nejib .
COMPTES RENDUS CHIMIE, 2016, 19 (04) :517-524
[6]   Insights into the modeling of adsorption isotherm systems [J].
Foo, K. Y. ;
Hameed, B. H. .
CHEMICAL ENGINEERING JOURNAL, 2010, 156 (01) :2-10
[7]   Process optimization of adsorption of Cr(VI) on activated carbons prepared from plant precursors by a two-level full factorial design [J].
Gottipati, Ramakrishna ;
Mishra, Susmita .
CHEMICAL ENGINEERING JOURNAL, 2010, 160 (01) :99-107
[8]   Experimental Design Technique on Removal of Hydrogen Sulfide using CaO-eggshells Dispersed onto Palm Kernel Shell Activated Carbon: Experiment, Optimization, Equilibrium and Kinetic Studies [J].
Habeeb, Omar Abed ;
Kanthasamy, Ramesh ;
Ali, Gomaa A. M. ;
Yunus, Rosli Bin Mohd .
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2017, 32 (02) :305-320
[9]  
Hamed Pourzolfaghar Hamed Pourzolfaghar, 2014, International Journal of Chemical and Environmental Engineering, V5, P22
[10]  
Hariz I. B., 2014, INT WATER TECHNOL J, V4, P264