Effect of Eu3+ codoping on upconversion luminescence in Y2O3:Er3+, Yb3+ nanocrystals

被引：15

作者：

Sheng, Y. Q. ^{[1
]}

Liu, J. ^{[1
]}

Xu, L. L. ^{[2
]}

Zhai, D. ^{[1
]}

Zhang, Z. G. ^{[1
]}

Cao, W. W. ^{[3
]}

机构：

[1] Harbin Inst Technol, Dept Phys, Harbin 150080, Peoples R China

[2] Harbin Normal Univ, Dept Phys, Harbin 150080, Peoples R China

[3] Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA

来源：

SOLID STATE COMMUNICATIONS | 2010年 / 150卷 / 23-24期

关键词：

Rare earth; UC luminescence; Energy transfer; ENERGY-TRANSFER; MECHANISMS; TB3+;

D O I：

10.1016/j.ssc.2010.03.004

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The influence of Eu3+ on the upconversion (UC) fluorescence of Er3+ in Y2O3:Er3+, Yb3+ nanocrystals was investigated. Room-temperature UC spectra show that the intensity ratio of red to green lights was increased from 8.6 to 19.3 with 1.0 mol% Eu3+ doping. Additionally, with the increase of Eu3+ ion concentration, the n values for both green and red UC emissions in Y2O3:Er3+, Yb3+ nanocrystals become larger. Our analysis shows that the energy transfer between Eu3+ and Er3+ ions is the main cause for the enhancement of H-2(11/2), S-4(3/2) -> F-4(9/2) and I-4(11/2) -> I-4(3/2) transitions of Er3+ ions. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1048 / 1051

页数：4

共 18 条

[1] Upconversion processes in Er3+-doped KPb2Cl5 -: art. no. 205203 [J].

Balda, R ;

Garcia-Adeva, AJ ;

Voda, M ;

Fernández, J .

PHYSICAL REVIEW B, 2004, 69 (20) :205203-1

[2] Two-color upconversion in rare-earth-ion-doped ZrO2 nanocrystals [J].

Chen, G. Y. ;

Zhang, Y. G. ;

Somesfalean, G. ;

Zhang, Z. G. ;

Sun, Q. ;

Wang, F. P. .

APPLIED PHYSICS LETTERS, 2006, 89 (16)

[3] Luminescence and visible upconversion in nanocrystalline ZrO2:Er3+ [J].

De la Rosa-Cruz, E ;

Díaz-Torres, LA ;

Rodríguez-Rojas, RA ;

Meneses-Nava, MA ;

Barbosa-García, O ;

Salas, P .

APPLIED PHYSICS LETTERS, 2003, 83 (24) :4903-4905

[4] Optical temperature sensing using upconversion fluorescence emission in Er3+/Yb3+-codoped chalcogenide glass [J].

dos Santos, PV ;

de Araujo, MT ;

Gouveia-Neto, AS ;

Neto, JAM ;

Sombra, ASB .

APPLIED PHYSICS LETTERS, 1998, 73 (05) :578-580

[5] Preparation process and upconversion luminescence of Er3+-doped glass ceramics containing Ba2LaF7 nanocrystals [J].

Fan, XP ;

Wang, J ;

Qiao, XS ;

Wang, MQ ;

Adam, JL ;

Zhang, XH .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (12) :5950-5954

[6] Upconversion lasing of a thulium-ion-doped fluorozirconate glass microsphere [J].

Fujiwara, H ;

Sasaki, K .

JOURNAL OF APPLIED PHYSICS, 1999, 86 (05) :2385-2388

[7] Luminescence properties of Y2O3 single crystals doped with Pr3+ or Tm3+ and codoped with Yb3+, Tb3+ or Ho3+ ions [J].

Guyot, Y ;

Moncorge, R ;

Merkle, LD ;

Pinto, A ;

McIntosh, B ;

Verdun, H .

OPTICAL MATERIALS, 1996, 5 (1-2) :127-136

[8] Semiconductor-laser-pumped high-power upconversion laser [J].

Heumann, E ;

Bär, S ;

Rademaker, K ;

Huber, G ;

Butterworth, S ;

Diening, A ;

Seelert, W .

APPLIED PHYSICS LETTERS, 2006, 88 (06)

[9] Preparation conditions and optical properties of rare earth ion (Er3+ and Eu3+)-doped alumina films by the aqueous sol-gel method [J].

Ishizaka, T ;

Kurokawa, Y .

JOURNAL OF APPLIED PHYSICS, 2001, 90 (01) :243-247

[10] Fluorescence upconversion properties of Er3+-doped TiO2 and BaTiO3 nanocrystallites [J].

Patra, A ;

Friend, CS ;

Kapoor, R ;

Prasad, PN .

CHEMISTRY OF MATERIALS, 2003, 15 (19) :3650-3655

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