Green alternative cosolvents to N-methyl-2-pyrrolidone in water polyurethane dispersions

被引：19
|
作者：
German, Lorena [1 ]
Maria Cuevas, Jose [1 ]
Cobos, Ruben [1 ]
Perez-Alvarez, Leyre [2 ]
Luis Vilas-Vilela, Jose [2 ,3 ]
机构：
[1] Basque Res & Technol Alliance BRTA, Gaiker Technol Ctr, Parque Tecnol Bizkaia,Edificio 202, E-48170 Zamudio, Spain
[2] Univ Basque Country, Fac Sci & Technol, Dept Phys Chem, Macromol Chem Grp LABQUIMAC,UPV EHU, Barrio Sarriena S-N, Leioa 48940, Spain
[3] Basque Ctr Mat Applicat & Nanostruct, BCMat, UPV EHU Sci Pk, Leioa 48940, Spain
来源：
RSC ADVANCES | 2021年 / 11卷 / 31期
基金：
欧盟地平线“2020”;
关键词：
GAMMA-VALEROLACTONE; DIHYDROLEVOGLUCOSENONE CYRENE; SOLVENT; BIOMASS; COATINGS; IMPROVE;
D O I：
10.1039/d1ra03157k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N-Methyl-2-pyrrolidone is a toxic dipolar aprotic solvent widely used in the synthesis of polyurethane dispersions (PUD). Since legislation strongly restricts this substance, green alternatives are essential. Dihydrolevoglucosenone and gamma valerolactone demonstrate comparable performance to that of NMP as cosolvent in the synthesis and the film forming process of PUD.
引用
收藏
页码：19070 / 19075
页数：6
相关论文
共 50 条
  • [41] Developmental toxicity of N-methyl-2-pyrrolidone administered orally to rats
    Saillenfait, AM
    Gallissot, F
    Langonné, I
    Sabaté, JP
    FOOD AND CHEMICAL TOXICOLOGY, 2002, 40 (11) : 1705 - 1712
  • [42] Workplace environmental exposure level guide: n-Methyl-2-pyrrolidone
    不详
    TOXICOLOGY AND INDUSTRIAL HEALTH, 2022, 38 (06) : 309 - 329
  • [43] Removal of N-Methyl-2-pyrrolidone by Photocatalytic Degradation in a Batch Reactor
    Zolfaghari, Alireza
    Mortaheb, Hamid Reza
    Meshkini, Fatemeh
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (16) : 9569 - 9576
  • [44] FATE OF ETHEPHON AND N-METHYL-2-PYRROLIDONE IN SOIL AND COTTON PLANTS
    SHAVER, TN
    ARCHIVES OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 1984, 13 (03) : 335 - 340
  • [45] Solubilization of naproxen using N-methyl-2-pyrrolidone or ethanol and β-cyclodextrin
    Hosseini, Nafiseh
    Hamidi, Samin
    Soleymani, Jafar
    Jouyban, Abolghasem
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2019, 57 (01) : 75 - 83
  • [46] Biomonitoring of Exposure to N-Methyl-2-Pyrrolidone in Workers of the Automobile Industry
    Meier, Swetlana
    Schindler, Birgit K.
    Koslitz, Stephan
    Koch, Holger M.
    Weiss, Tobias
    Kaefferlein, Heiko U.
    Bruening, Thomas
    ANNALS OF OCCUPATIONAL HYGIENE, 2013, 57 (06): : 766 - 773
  • [47] Sustainable Catalytic Synthesis for a Bio-Based Alternative to the Reach-Restricted N-Methyl-2-Pyrrolidone
    Barbaro, Pierluigi
    Liguori, Francesca
    Oldani, Claudio
    Moreno-Marrodan, Carmen
    ADVANCED SUSTAINABLE SYSTEMS, 2020, 4 (05):
  • [48] Solubility, dissolution thermodynamics and preferential solvation of sulfadiazine in (N-methyl-2-pyrrolidone plus water) mixtures
    Osorio, Irmis P.
    Martinez, Fleming
    Pena, Maria A.
    Jouyban, Abolghasem
    Acree, William E., Jr.
    JOURNAL OF MOLECULAR LIQUIDS, 2021, 330
  • [49] COMPONENT MOBILITY ANALYSIS IN THE MEMBRANE-FORMING SYSTEM WATER N-METHYL-2-PYRROLIDONE POLYETHERSULFONE
    TKACIK, G
    ZEMAN, L
    JOURNAL OF MEMBRANE SCIENCE, 1987, 31 (2-3) : 273 - 288
  • [50] An analysis of the N-methyl-2-pyrrolidone: water complex using computational and matrix isolation FTIR methods
    Mcmurray, Isiah M.
    Nettles, Joseph R.
    Uzelmeier, Aaron W.
    Swartz, Jeremy A.
    Newby, Josh J.
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2025, 408
12345