Green alternative cosolvents to N-methyl-2-pyrrolidone in water polyurethane dispersions

被引:19
|
作者
German, Lorena [1 ]
Maria Cuevas, Jose [1 ]
Cobos, Ruben [1 ]
Perez-Alvarez, Leyre [2 ]
Luis Vilas-Vilela, Jose [2 ,3 ]
机构
[1] Basque Res & Technol Alliance BRTA, Gaiker Technol Ctr, Parque Tecnol Bizkaia,Edificio 202, E-48170 Zamudio, Spain
[2] Univ Basque Country, Fac Sci & Technol, Dept Phys Chem, Macromol Chem Grp LABQUIMAC,UPV EHU, Barrio Sarriena S-N, Leioa 48940, Spain
[3] Basque Ctr Mat Applicat & Nanostruct, BCMat, UPV EHU Sci Pk, Leioa 48940, Spain
基金
欧盟地平线“2020”;
关键词
GAMMA-VALEROLACTONE; DIHYDROLEVOGLUCOSENONE CYRENE; SOLVENT; BIOMASS; COATINGS; IMPROVE;
D O I
10.1039/d1ra03157k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
N-Methyl-2-pyrrolidone is a toxic dipolar aprotic solvent widely used in the synthesis of polyurethane dispersions (PUD). Since legislation strongly restricts this substance, green alternatives are essential. Dihydrolevoglucosenone and gamma valerolactone demonstrate comparable performance to that of NMP as cosolvent in the synthesis and the film forming process of PUD.
引用
收藏
页码:19070 / 19075
页数:6
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