Direct synthesis of Zn-ZSM-5 with novel morphology

被引:91
作者
Wang, Ligang
Sang, Shiyun
Meng, Shuanghe
Zhang, Ying
Qi, Yue
Liu, Zhongmin [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
关键词
Zn-ZSM-5; Zn(NH3)(4)](2+); n-butylamine; coordination;
D O I
10.1016/j.matlet.2006.07.097
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Zinc-containing ZSM-5 zeolite with novel morphology was firstly synthesized in a one-step route using [Zn(NH3)(4)](2+) aqueous solution as zinc resource and n-butylamine as template. The materials were characterized by XRD, SEM, diffuse reflectance UV-vis spectra, FTIR for pyridine adsorption. The results showed that the formation of this novel structure might be related to the introduction of [Zn(NH3)(4)](2+) aqueous solution and the zinc existent state in zeolite. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:1675 / 1678
页数:4
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