Soluble Carbon Nanotubes and Application to Electrochemistry

被引:4
作者
Fujigaya, Tsuyohiko [1 ]
Tanaka, Yasuhiko [1 ]
Nakashima, Naotoshi [1 ,2 ]
机构
[1] Kyushu Univ, Dept Appl Chem, Grad Sch Engn, Fukuoka 8190395, Japan
[2] Japan Sci & Technol Agcy, CREST, Chiyoda Ku, Tokyo 1020075, Japan
关键词
Carbon Nanotubes; Solubilization; Functionalization; Electrochemistry; Electronic States; Electrocatalyst; Fuel Cell; DONOR-ACCEPTOR NANOHYBRIDS; NONCOVALENT SIDEWALL-FUNCTIONALIZATION; POLYCYCLIC AROMATIC-HYDROCARBONS; SIZE-EXCLUSION CHROMATOGRAPHY; FUEL-CELL ELECTROCATALYST; IN-SITU POLYMERIZATION; IR SPECTRAL PROPERTIES; INDIVIDUAL DISSOLUTION; ABSORPTION-SPECTROSCOPY; MECHANICAL-PROPERTIES;
D O I
10.5796/electrochemistry.78.2
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
One of the key issues in the utilization of carbon nanotubes (CNTs) for basic researches as well as their applications is to develop a methodology to solubilize/disperse them in solvents. In this review articles, we first summarize individual solubilization of single-walled carbon nanotubes (SWNTs) in solvents using surfactants, polycylcic aromatic molecules, DNA and condensed polymers. We then describe a novel method determining the electronic states of individually dissolved SWNTs having an own chirality index based on the analysis of Nernst equation. We also introduce our recent approach toward the fabrication of a novel catalyst for fuel cell that works at a non-humid atmosphere using solubilized CNTs as material.
引用
收藏
页码:2 / 15
页数:14
相关论文
共 173 条
[51]   Functional single-wall carbon nanotube nanohybrids-associating SWNTs with water-soluble enzyme model systems [J].
Guldi, DM ;
Rahman, GMA ;
Jux, N ;
Balbinot, D ;
Hartnagel, U ;
Tagmatarchis, N ;
Prato, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (27) :9830-9838
[52]   Novel photoactive single-walled carbon nanotube-porphyrin polymer wraps: Efficient and long-lived intracomplex charge separation [J].
Guldi, DM ;
Taieb, H ;
Rahman, GMA ;
Tagmatarchis, N ;
Prato, M .
ADVANCED MATERIALS, 2005, 17 (07) :871-+
[53]   CNT-CdTe versatile donor-acceptor nanohybrids [J].
Guldi, DM ;
Rahman, GMA ;
Sgobba, V ;
Kotov, NA ;
Bonifazi, D ;
Prato, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (07) :2315-2323
[54]   Multiwalled carbon nanotubes in donor-acceptor nanohybrids - towards long-lived electron transfer products [J].
Guldi, DM ;
Rahman, GMA ;
Jux, N ;
Balbinot, D ;
Tagmatarchis, N ;
Prato, M .
CHEMICAL COMMUNICATIONS, 2005, (15) :2038-2040
[55]   Covalently porphyrin-functionalized single-walled carbon nanotubes: a novel photoactive and optical limiting donor-acceptor nanohybrid [J].
Guo, Zhen ;
Du, Feng ;
Ren, Dongmei ;
Chen, Yongsheng ;
Zheng, Jianyu ;
Liu, Zhibo ;
Tian, Jianguo .
JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (29) :3021-3030
[56]   NEW ONE-DIMENSIONAL CONDUCTORS - GRAPHITIC MICROTUBULES [J].
HAMADA, N ;
SAWADA, S ;
OSHIYAMA, A .
PHYSICAL REVIEW LETTERS, 1992, 68 (10) :1579-1581
[57]   DNA-wrapped single-walled carbon nanotubes as rigid templates for assembling linear gold nanoparticle arrays [J].
Han, Xiaogang ;
Li, Yulin ;
Deng, Zhaoxiang .
ADVANCED MATERIALS, 2007, 19 (11) :1518-+
[58]   Ordered assembly of protonated porphyrin driven by single-wall carbon nanotubes. J- and H-aggregates to nanorods [J].
Hasobe, T ;
Fukuzumi, S ;
Kamat, PV .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (34) :11884-11885
[59]   Organized assemblies of single wall carbon nanotubes and porphyrin for photochemical solar cells: Charge injection from excited porphyrin into single-walled carbon nanotubes [J].
Hasobe, Taku ;
Fukuzumi, Shunichi ;
Kamat, Prashant V. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (50) :25477-25484
[60]   Layer-by-layer fabrication and characterization of DNA-wrapped single-walled carbon nanotube particles [J].
He, PG ;
Bayachou, M .
LANGMUIR, 2005, 21 (13) :6086-6092