Environmentally friendly methodologies of nanostructure synthesis

被引:292
作者
Mao, Yuanbing
Park, Tae-Jin
Zhang, Fen
Zhou, Hongjun
Wong, Stanislaus S. [1 ]
机构
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
[2] Brookhaven Natl Lab, Condensed Matter Phys & Mat Sci Dept, Upton, NY 11973 USA
关键词
green chemistry; hydrothermal synthesis; molten-salt synthesis; nanostructures; template synthesis;
D O I
10.1002/smll.200700048
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Environmentally friendly synthetic methodologies have gradually been implemented as viable techniques in the synthesis of a range of nanostructures. In this work, we focus on the application of green-chemistry principles to the synthesis of complex metal oxide and fluoride nanostructures. In particular, we describe advances in the use of the molten-salt synthetic methods, hydrothermal protocols, and template-directed techniques as environmentally sound, socially responsible, and cost-effective methodologies that allow us to generate nanomaterials without the need to sacrifice sample quality, purity, and crystallinity, while allowing control over size, shape, and morphology.
引用
收藏
页码:1122 / 1139
页数:18
相关论文
共 206 条
[1]   Nanosize semiconductors for photooxidation [J].
Abrams, BL ;
Wilcoxon, JP .
CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES, 2005, 30 (03) :153-182
[2]   Shape-controlled synthesis of colloidal platinum nanoparticles [J].
Ahmadi, TS ;
Wang, ZL ;
Green, TC ;
Henglein, A ;
ElSayed, MA .
SCIENCE, 1996, 272 (5270) :1924-1926
[3]   Perspectives on the physical chemistry of semiconductor nanocrystals [J].
Alivisatos, AP .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13226-13239
[4]   Origins, current status, and future challenges of green chemistry [J].
Anastas, PT ;
Kirchhoff, MM .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694
[5]   Structures in the system CaTiO3/SrTiO3 [J].
Ball, CJ ;
Begg, BD ;
Cookson, DJ ;
Thorogood, GJ ;
Vance, ER .
JOURNAL OF SOLID STATE CHEMISTRY, 1998, 139 (02) :238-247
[6]   Observation of Fano asymmetry in Raman spectra of SrTiO3 and CaxSr1-xTiO3 perovskite nanocubes [J].
Banerjee, Sarbajit ;
Kim, Dae-In ;
Robinson, Richard D. ;
Herman, Irving P. ;
Mao, Yuanbing ;
Wong, Stanislaus S. .
APPLIED PHYSICS LETTERS, 2006, 89 (22)
[7]   Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products [J].
Banfield, JF ;
Welch, SA ;
Zhang, HZ ;
Ebert, TT ;
Penn, RL .
SCIENCE, 2000, 289 (5480) :751-754
[8]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[9]   The effect of hydrothermal conditions on the mesoporous structure of TiO2 nanotubes [J].
Bavykin, DV ;
Parmon, VN ;
Lapkin, AA ;
Walsh, FC .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (22) :3370-3377
[10]   In-vitro crystallization of calcium carbonate in the presence of biological additives -: Comparison of the ammonium carbonate method with double-diffusion techniques [J].
Becker, A ;
Becker, W ;
Marxen, JC ;
Epple, M .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (12-13) :2305-2311