Metal-organic framework-derived nanocomposites for electrocatalytic hydrogen evolution reaction

被引：274
作者：
Chen, Ziliang [1 ]
Qing, Huilin [1 ,2 ]
Zhou, Kun [3 ]
Sun, Dalin [1 ]
Wu, Renbing [1 ]
机构：
[1] Fudan Univ, Dept Mat Sci, 220 Handan Rd, Shanghai 200433, Peoples R China
[2] Fudan Univ, Dept Macromol Sci, 220 Handan Rd, Shanghai 200433, Peoples R China
[3] Nanyang Technol Univ, Sch Mech & Aerosp Engn, 50 Nanyang Ave, Singapore 639798, Singapore
来源：
PROGRESS IN MATERIALS SCIENCE | 2020年 / 108卷
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Metal-organic framework; Transition metal-based compounds; Carbon matrix; Nanocomposites; Electrocatalyst; Hydrogen evolution reaction; NITROGEN-DOPED CARBON; HIGHLY EFFICIENT ELECTROCATALYSTS; HIGH-PERFORMANCE ELECTROCATALYST; ALIGNED MOF ARRAYS; IN-SITU FORMATION; OXYGEN EVOLUTION; POROUS CARBON; BIFUNCTIONAL ELECTROCATALYSTS; WATER OXIDATION; QUANTUM DOTS;
D O I：
10.1016/j.pmatsci.2019.100618
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The rapid development of hydrogen energy is strongly dependent on the economic and efficient production of hydrogen. The electrocatalytic splitting of water to molecular hydrogen via the hydrogen evolution reaction (HER) provides an appealing solution for producing high-purity hydrogen, but low-cost and highly active electrocatalysts are required for HER. Among currently investigated HER electrocatalysts, metal-organic framework (MOF)-derived nanocomposites constructed from transition metals (TMs)/TM compounds (TMCs) and carbon materials offer extremely promising and attractive HER activities because of their unique properties, such as tunable compositions, readily regulated electronic structures, controllable morphologies, and diverse configuration. Herein, this article provides a comprehensive overview of MOF-derived nanocomposites as HER electrocatalysts for water splitting. It begins with the introduction of the fundamentals of electrocatalytic HER. Afterwards, several ingeniously designed strategies for improved MOF-derived HER electrocatalysts are meticulously summarized and discussed, with special emphasis on the component manipulation of the TMs/TMCs, carbon matrix modifications, morphology tuning and electrode configuration engineering. Finally, future perspectives on the development of these nanocomposites as HER electrocatalysts are proposed.
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页数：49
相关论文
共 314 条
[1]   Direct growth of ternary Ni-Fe-P porous nanorods onto nickel foam as a highly active, robust bi-functional electrocatalyst for overall water splitting [J].
Ahn, Sung Hoon ;
Manthiram, Arumugam .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (06) :2496-2503
[2]   Ultrathin Graphene Layers Encapsulating Nickel Nanoparticles Derived Metal-Organic Frameworks for Highly Efficient Electrocatalytic Hydrogen and Oxygen Evolution Reactions [J].
Ai, Lunhong ;
Tian, Tian ;
Jiang, Jing .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (06) :4771-4777
[3]   Metal-Organic Framework Derived Carbon Nanotube Grafted Cobalt/Carbon Polyhedra Grown on Nickel Foam: An Efficient 3D Electrode for Full Water Splitting [J].
Aijaz, Arshad ;
Masa, Justus ;
Roesler, Christoph ;
Xia, Wei ;
Weide, Philipp ;
Fischer, Roland A. ;
Schuhmann, Wolfgang ;
Muhler, Martin .
CHEMELECTROCHEM, 2017, 4 (01) :188-193
[4]   Oriented Growth of ZIF-67 to Derive 2D Porous CoPO Nanosheets for Electrochemical-/Photovoltage-Driven Overall Water Splitting [J].
Anandhababu, Ganesan ;
Huang, Yiyin ;
Babu, Dickson D. ;
Wu, Maoxiang ;
Wang, Yaobing .
ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (09)
[5]   Recent Trends and Perspectives in Electrochemical Water Splitting with an Emphasis on Sulfide, Selenide, and Phosphide Catalysts of Fe, Co, and Ni: A Review [J].
Anantharaj, Sengeni ;
Ede, Sivasankara Rao ;
Sakthikumar, Kuppan ;
Karthick, Kannimuthu ;
Mishra, Soumyaranjan ;
Kundu, Subrata .
ACS CATALYSIS, 2016, 6 (12) :8069-8097
[6]  
[Anonymous], 2018, ADV MATER
[7]   Formation of Yolk-Shelled Nickel-Cobalt Selenide Dodecahedral Nanocages from Metal-Organic Frameworks for Efficient Hydrogen and Oxygen Evolution [J].
Ao, Kelong ;
Dong, Jiancheng ;
Fan, Chonghui ;
Wang, Di ;
Cai, Yibing ;
Li, Dawei ;
Huang, Fenglin ;
Wei, Qufu .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (08) :10952-+
[8]   Splitting Water with Cobalt [J].
Artero, Vincent ;
Chavarot-Kerlidou, Murielle ;
Fontecave, Marc .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) :7238-7266
[9]   Surface Polarization Matters: Enhancing the Hydrogen-Evolution Reaction by Shrinking Pt Shells in Pt-Pd-Graphene Stack Structures [J].
Bai, Song ;
Wang, Chengming ;
Deng, Mingsen ;
Gong, Ming ;
Bai, Yu ;
Jiang, Jun ;
Xiong, Yujie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (45) :12120-12124
[10]   Updates on the development of nanostructured transition metal nitrides for electrochemical energy storage and water splitting [J].
Balogun, Muhammad-Sadeeq ;
Huang, Yongchao ;
Qiu, Weitao ;
Yang, Hao ;
Ji, Hongbing ;
Tong, Yexiang .
MATERIALS TODAY, 2017, 20 (08) :425-451
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