Hydrothermal synthesis of Pt-Ag alloy nano-octahedra and their enhanced electrocatalytic activity for the methanol oxidation reaction

被引:54
作者
Fu, Geng-Tao [2 ]
Ma, Ru-Guang [3 ]
Gao, Xue-Qing [1 ]
Chen, Yu [1 ,2 ]
Tang, Ya-Wen [2 ]
Lu, Tian-Hong [2 ]
Lee, Jong-Min [3 ]
机构
[1] Shaanxi Normal Univ, Sch Mat Sci & Engn, Xian 710062, Peoples R China
[2] Nanjing Normal Univ, Jiangsu Key Lab New Power Batteries, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Anal & Testing Ctr,Sch Chem & Mat Sci, Nanjing 210023, Jiangsu, Peoples R China
[3] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore
关键词
OXYGEN REDUCTION REACTION; WATER-BASED SYNTHESIS; ONE-POT SYNTHESIS; OPTICAL-PROPERTIES; GOLD OCTAHEDRA; NANOPARTICLES; PLATINUM; NANOCRYSTALS; SURFACE; NANOSTRUCTURES;
D O I
10.1039/c4nr03617d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The high-quality Pt48Ag52 alloy nano-octahedra are synthesized via one-pot hydrothermal method. The catalytic growth of Ag-0 atoms on Pt nuclei and selective oxidative etching on the Ag-0 atoms contribute to the formation of alloy nano-octahedra. Pt48Ag52 alloy nano-octahedra show excellent electrocatalytic activity and durability for the methanol oxidation reaction (MOR).
引用
收藏
页码:12310 / 12314
页数:5
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