Palladium(II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide

被引：17
|
作者：
Wojcinski, LM [1 ]
Boyer, MT [1 ]
Sen, A [1 ]
机构：
[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA
来源：
INORGANICA CHIMICA ACTA | 1998年 / 270卷 / 1-2期
关键词：
palladium complexes; alkyl complexes; copolymerization; terpolymerization; sulfur dioxide;
D O I：
10.1016/S0020-1693(97)05856-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cationic palladium(II) complexes of the type [L2Pd(CH3)(CH3CN)]BF4 (L-2 =1,3-bis(diphenylphosphino)propane (Dppp) or 1,2-bis( 2,5-dimethylphospholano)benzene (Me-Duphos)) were found to catalyze the alternating copolymerization of ethene, propene and cyclopentene with sulfur dioxide, as well as the terpolymerization of ethene, propene and sulfur dioxide. The resultant materials are high melting solids with an alternating alkene-SO2 structure and an exclusive head-to-tail enchainment for propene. (C) 1998 Elsevier Science S.A.
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收藏
页码：8 / 11
页数：4
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