Electrooptical and dielectric properties of comb-shaped poly(methacrylates) with various dipole architecture of mesogenic groups

被引:0
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作者
Tsvetkov, NV
Kovshik, AP
Kovshik, SA
Kurakina, VO
Ksenofontov, IV
Ryumtsev, EI
Barmatov, EB
Yuntsze, T
Shibaev, VP
机构
[1] St Petersburg State Univ, Inst Phys, St Petersburg 198904, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A number of mesogenic poly(methacrylates) with the varying dipole architecture of mesogenic nuclei were studied by equilibrium electric birefringence, dielectric measurements, and refractometry. It was shown that the introduction of halogen substituents into the mesogenic nuclei leads to a reduction in the dipole moments and the Kerr constant for the polymers under study. The effect of the dipole structure of macromolecules on the electrooptical characteristics of the studied poly(methacrylates) was analyzed.
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页码:718 / 720
页数:3
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