Catalytic Activity Studies of Aminocarbonyl Group Containing Hoveyda-Grubbs-Type Complexes for the Syntheses of Herbarumin I and Stagonolide A

被引：27

作者：

Mohapatra, Debendra K. ^{[1
]}

Somaiah, R. ^{[1
]}

Rao, M. Mallikarjuna ^{[1
]}

Caijo, Frederic ^{[2
]}

Mauduit, Marc ^{[2
]}

Yadav, J. S. ^{[1
]}

机构：

[1] Indian Inst Chem Technol CSIR, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India

[2] Ecole Natl Super Chim Rennes, F-35700 Rennes, France

来源：

SYNLETT | 2010年 / 08期

关键词：

decanolides; stagonolides; herbarumin I; Wittig reaction; ring-closing metathesis; RING-CLOSING METATHESIS; ENANTIOSELECTIVE TOTAL-SYNTHESIS; OLEFIN METATHESIS; PHYTOTOXIC NONENOLIDE; STAGONOSPORA-CIRSII; PHOMA-PUTAMINUM; STEREOSELECTIVE-SYNTHESIS; POTENTIAL MYCOHERBICIDE; ASCOCHYTA-PINODES; ORGANIC-SYNTHESIS;

D O I：

10.1055/s-0029-1219807

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalytic activity of four aminocarbonyl group containing 'boomerang'-type ring-closing metathesis catalysts have been studied for ten-membered lactone and compared well with the Grubbs I and II as well as the Hoveyda-Grubbs catalysts. The activity was found to be superior to the above three ring-closing metathesis catalysts and suggesting novel stereoselective total syntheses of herbarumin I and stagonolide A.

引用

页码：1223 / 1226

页数：4

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