A novel ionic liquid supported organocatalyst of pyrrolidine amide: Synthesis and catalyzed Claisen-Schmidt reaction

被引:70
作者
Yang, Shang-Dong [1 ]
Wu, Lu-Yong [1 ]
Yan, Ze-Yi [1 ]
Pan, Zhen-Liang [1 ]
Liang, Yong-Min [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
关键词
ionic liquid; pyrrolidine amide; alpha; beta-unsaturated ketone; organocatalyst;
D O I
10.1016/j.molcata.2006.11.039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel organocatalyst of pyrrolidine amide based on room temperature ionic liquid (RTIL) has been developed to perform Claisen-Schmidt reaction with acetone or cyclic ketone and various aromatic aldehydes at room temperature under free-solvent condition. The (E)-alpha,beta-unsaturated ketone products were obtained in good yields. The ionic liquid supported pyrrolidine amide catalyst can be readily recovered and reused successfully without any significant loss of catalytic activity. (c) 2007 Published by Elsevier B.V.
引用
收藏
页码:107 / 111
页数:5
相关论文
共 50 条
  • [21] Novel ionic liquid supported synthesis of platinum-based electrocatalysts on multiwalled carbon nanotubes
    Zhao, ZW
    Guo, ZP
    Ding, J
    Wexler, D
    Ma, ZF
    Zhang, DY
    Liu, HK
    ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (02) : 245 - 250
  • [22] Synthesis, characterization and catalytic application of a novel polyethylene-supported Fe/ionic liquid complex
    Elhamifar, Davar
    Elhamifar, Dawood
    Shojaeipoor, Frood
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2017, 426 : 198 - 204
  • [23] Facile Synthesis of Acetal Over a Supported Novel Bronsted and Lewis Acid Ionic Liquid Catalyst
    Liu, Ruifeng
    Dai, Liming
    Zhao, Qian
    Xie, Yingjie
    Jiang, Tingshun
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2019, 19 (08) : 4396 - 4405
  • [25] A novel green synthesis of quinolines through acid-catalyzed Friedlander reaction in ionic liquids
    Zhang, XY
    Fan, XS
    Wang, JJ
    Li, YZ
    CHINESE CHEMICAL LETTERS, 2004, 15 (10) : 1170 - 1172
  • [26] A novel chemoenzymatic synthesis of propyl caffeate using lipase-catalyzed transesterification in ionic liquid
    Pang, Na
    Gu, Shuang-Shuang
    Wang, Jun
    Cui, Hong-Sheng
    Wang, Fang-Qin
    Liu, Xi
    Zhao, Xing-Yu
    Wu, Fu-An
    BIORESOURCE TECHNOLOGY, 2013, 139 : 337 - 342
  • [27] Design and development of novel fluorescent oxo-fluoro quinoline (E)-chalcone derivatives via Claisen-Schmidt reaction using Al-SrTiO3 as a catalyst and its BSA protein binding studies
    Murugesan, Arul
    Samikannu, Prabu
    Ilanchelian, Malaichamy
    Robert, M. Gengan
    SYNTHETIC COMMUNICATIONS, 2023, 53 (14) : 1104 - 1125
  • [28] Ionic liquid catalyzed one pot four-component coupling reaction for the synthesis of functionalized pyrroles
    Gupta, Neeru
    Singh, Kamal N.
    Singh, Jasvinder
    JOURNAL OF MOLECULAR LIQUIDS, 2014, 199 : 470 - 473
  • [29] An expedient sequential one-pot four component synthesis of novel steroidal spiro-pyrrolidine heterocycles in ionic liquid
    Gavaskar, D.
    Babu, A. R. Suresh
    Raghunathan, R.
    Dharani, M.
    Balasubramanian, S.
    STEROIDS, 2016, 109 : 1 - 6
  • [30] Ultrasound Promoted and Ionic Liquid Catalyzed Cyclocondensation Reaction for the Synthesis of 4(3H)-Quinazolinones
    Pawar, Omprakash B.
    Chavan, Fulchand R.
    Sakate, Sachin S.
    Shinde, Narayan D.
    CHINESE JOURNAL OF CHEMISTRY, 2010, 28 (01) : 69 - 71