Nanodomain cubic copper (I) oxide as reusable catalyst for the synthesis of amides by amidation of aryl halides with isocyanides

被引：17

作者：

Sarkar, Swarbhanu ^{[1
]}

Pal, Rammyani ^{[1
]}

Roy, Manas ^{[2
]}

Chatterjee, Nivedita ^{[1
]}

Sarkar, Sabyasachi ^{[3
]}

Sen, Asish Kumar ^{[1
]}

机构：

[1] CSIR, Div Chem, Indian Inst Chem Biol, Kolkata 700032, India

[2] Lovely Profess Univ, Dept Chem, Phagwara 144411, Punjab, India

[3] Indian Inst Engn Sci & Technol, Dept Chem, Sibpur 711103, Howrah, India

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 04期

关键词：

Copper (1) oxide nanoparticle; Reusable catalyst; Amidation; Aryl halides; Isocyanide; ONE-POT SYNTHESIS; LIGAND-FREE; CARBON-MONOXIDE; CU2O NANOCUBES; HECK REACTIONS; GREEN APPROACH; PALLADIUM; CARBONYLATION; (Z)-3-METHYLENEISOINDOLINE-1-ONES; AMINOCARBONYLATIONS;

D O I：

10.1016/j.tetlet.2014.12.060

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An environmentally benign chemical process for the C-C coupling of aryl halides with isocyanides in aqueous medium has been developed using cubic copper (I) oxide nanoparticles as reusable catalyst. The use of nano-catalyst eliminates the use of any stabilizing ligands or additives as well as the use of organic solvents. The catalyst exhibited comparable efficiency up to three recycles and was found to be very effective for the synthesis of varied amides leading to biologically significant scaffold. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：623 / 626

页数：4

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