Mixed crystals in the system Cu3Mo2O9/Zn3Mo2O9

被引：15
|
作者：
Reichelt, W
Steiner, U
Söhnel, T
Oeckler, O
Duppel, V
Kienle, L
机构：
[1] Tech Univ Dresden, Inst Anorgan Chem, D-01062 Dresden, Germany
[2] Univ Auckland, Dept Chem, Auckland 1, New Zealand
[3] Univ Munich, Dept Chem & Biochem, Munich, Germany
[4] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 2-3期
关键词：
copper; zinc; molybdates; chemical vapor transport;
D O I：
10.1002/zaac.200400454
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two mixed crystal series exist in the System Cu3Mo2O9/Zn3Mo2O9: Cu3(1-x)Zn3xMo2O9 with x = 0 to x = 0.8 and x = 0.88 to x = 1, respectively. Single crystals of Cu3(1-x)Zn3xMo2O9 (x = 0 to x = 0.8) have been obtained by chemical vapor transport in a temperature gradient 973K-->873K using Cl-2 as transport agents. The solid solution series were characterized using X-ray powder diffraction, single crystal investigations and HRTEM investigations.
引用
收藏
页码：596 / 603
页数：8
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