Morphology control and optical properties of organic nanostructures based on thermotropic liquid crystalline benzoylated bacterial cellulose

被引:4
作者
Zhou, Mingru [1 ]
Duan, Xiaohui [1 ]
Ma, Yongjun [1 ]
Zhou, Yong [2 ]
Pei, Chonghua [1 ]
Luo, Qingping [1 ]
机构
[1] SW Univ Sci & Technol, Sch Mat Sci & Engn, Mianyang 621010, Peoples R China
[2] Nanjing Univ, Dept Mat Sci & Engn, Natl Lab Solid State Microstruct, ERERC, Nanjing 210093, Peoples R China
关键词
Bacterial cellulose; Thermotropic liquid crystalline; Organic nanostructure; Reprecipitaion; Fluorescence; REPRECIPITATION METHOD; WAVE-GUIDES; NANOWIRES; NANOPARTICLES; MOLECULES; GROWTH; MICROCRYSTALS; NANORIBBONS; FABRICATION; MICROTUBES;
D O I
10.1016/j.carbpol.2009.12.032
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Organic nanostructures with different morphologies (nanoplatelets, nanotubes, and nanoparticles) of thermotropic liquid crystalline benzoylated bacterial cellulose (BBC) have been prepared with a reprecipitation method by dropwising tetrahydrofuran (THF) solution of BBC into water. The BBC concentration in THE proves crucial for the shapes of assembled BBC nanostructures. These novel BBC nanostructures exhibit apparent UV-vis blue-shifted in absorption peaks and enhanced fluorescence intensity up to 30-60 times compared with THF dilute solution of BBC. The formation mechanism of different nanostructures was tentatively proposed based on the BBC molecular structure. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:551 / 554
页数:4
相关论文
共 36 条
[1]   Enhanced emission and its switching in fluorescent organic nanoparticles [J].
An, BK ;
Kwon, SK ;
Jung, SD ;
Park, SY .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (48) :14410-14415
[2]   Nanobelt self-assembly from an organic n-type semiconductor: Propoxyethyl-PTCDI [J].
Balakrishnan, K ;
Datar, A ;
Oitker, R ;
Chen, H ;
Zuo, JM ;
Zang, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (30) :10496-10497
[3]   UV solvatochromic shifts of 4-hydroxy-benzophenone and 2,4-dihydroxy-benzophenone in ethanol-acetonitrile mixtures [J].
Blanco, SE ;
Gasull, EI ;
Ferretti, FH .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (13) :2985-2995
[4]   Study of characterization and application on the binding between 5-iodouridine with HSA by spectroscopic and modeling [J].
Cui, Fengling ;
Zhang, Qiangzhai ;
Yan, Yinghua ;
Yao, Xiaojun ;
Qu, Guirong ;
Lu, Yan .
CARBOHYDRATE POLYMERS, 2008, 73 (03) :464-472
[5]   Synthesis of organic nanoparticles in different W/O microemulsions [J].
Debuigne, F ;
Jeunieau, L ;
Wiame, M ;
Nagy, JB .
LANGMUIR, 2000, 16 (20) :7605-7611
[6]   HIGH-RATE, GAS-PHASE GROWTH OF MOS2 NESTED INORGANIC FULLERENES AND NANOTUBES [J].
FELDMAN, Y ;
WASSERMAN, E ;
SROLOVITZ, DJ ;
TENNE, R .
SCIENCE, 1995, 267 (5195) :222-225
[7]   Size effects on the optical properties of organic nanoparticles [J].
Fu, HB ;
Yao, JN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (07) :1434-1439
[8]   Solvent polarizability and anisotropy effects on the photophysical behavior of oxazine 1: An appropriate polarizability indicator dye [J].
Ghanadzadeh, A. ;
Zeini, A. ;
Kashef, A. ;
Moghadam, M. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 73 (02) :324-329
[9]   Low-voltage organic transistors with an amorphous molecular gate dielectric [J].
Halik, M ;
Klauk, H ;
Zschieschang, U ;
Schmid, G ;
Dehm, C ;
Schütz, M ;
Maisch, S ;
Effenberger, F ;
Brunnbauer, M ;
Stellacci, F .
NATURE, 2004, 431 (7011) :963-966
[10]   Syntheses and spectral properties of non-planar bis(styryl)diazepine fluorescent dyes and related derivatives [J].
Horiguchi, E ;
Shirai, K ;
Matsuoka, M ;
Matsui, M .
DYES AND PIGMENTS, 2002, 53 (01) :45-55