Luminescent staircase copper(I) coordination polymer based on planar Cu3I3

被引:40
作者
Kim, Tae Ho
Shin, Yong Woon
Kim, Jae Sang
Lee, Shim Sung
Kim, Jineun [1 ]
机构
[1] Gyeongsang Natl Univ, Dept Chem BK21, Jinju 660701, South Korea
[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 660701, South Korea
关键词
copper(I) iodide; coordination polymer; dithioether ligand; crystal structure; supramolecular assembly;
D O I
10.1016/j.inoche.2007.03.009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Copper(l) coordination polymer [CU3I3L](n) (1) has been synthesized by the reaction of CuI and 1,4-bis((cyclohexylthio)acetyl)piperazine (L). Structural and photophysical studies of I in solid state are reported. The bonding of Cu3I3 produces staircase polymers interconnected by the sulfur atoms of L. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:717 / 719
页数:3
相关论文
共 30 条
[1]   New compounds with extended structure lattices from the reactions of cuprous iodide with cyclic polydisulfides [J].
Adams, RD ;
Huang, MS ;
Johnson, S .
POLYHEDRON, 1998, 17 (17) :2775-2780
[2]   Luminescence ranging from red to blue:: A series of copper(I)-halide complexes having rhombic {Cu2(μ-X)2} (X=Br and I) units with N-heteroaromatic ligands [J].
Araki, H ;
Tsuge, K ;
Sasaki, Y ;
Ishizaka, S ;
Kitamura, N .
INORGANIC CHEMISTRY, 2005, 44 (26) :9667-9675
[3]   VAN DER WAALS VOLUMES + RADII [J].
BONDI, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+
[4]   Discrete molecular and extended polymeric copper(I) halide complexes of tetradentate thioether macrocycles [J].
Brooks, NR ;
Blake, AJ ;
Champness, NR ;
Cooke, PA ;
Hubberstey, P ;
Proserpio, DM ;
Wilson, C ;
Schröder, M .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (04) :456-465
[5]  
Bruker, 1998, SHELXTL PC VERS 5 10
[6]   New structural motifs, unusual quenching of the emission, and second harmonic generation of copper(I) iodide polymeric or oligomeric adducts with para-substituted pyridines or trans-stilbazoles [J].
Cariati, E ;
Roberto, D ;
Ugo, R ;
Ford, PC ;
Galli, S ;
Sironi, A .
INORGANIC CHEMISTRY, 2005, 44 (11) :4077-4085
[7]   X-ray structures and emissive and second-order nonlinear optical properties of two inorganic-organic polymeric adducts of CuI with 4-acetylpyridine.: The role of both "intrastrand" charge transfers and structural motifs on the nonlinear optical response of Cu(I) polymeric adducts with pseudoaromatic η1-nitrogen donor ligands [J].
Cariati, E ;
Roberto, D ;
Ugo, R ;
Ford, PC ;
Galli, S ;
Sironi, A .
CHEMISTRY OF MATERIALS, 2002, 14 (12) :5116-5123
[8]   Synthesis, crystal structures and dynamic NMR studies of novel trinuclear copper(I) halide complexes with 2,5-bis[(diphenylphosphino)-methyl]thiophene [J].
Chen, BL ;
Mok, KF ;
Ng, SC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (17) :2861-2866
[9]   COORDINATION CHEMISTRY OF THIOETHER PYRIDAZINE MACROCYCLES .2. SYNTHESIS, STRUCTURAL AND SPECTROSCOPIC STUDIES OF DINUCLEAR COPPER(II) AND POLYNUCLEAR COPPER(I) AND SILVER(I) COMPLEXES OF A TETRATHIAPYRIDAZINOPHANE MACROCYCLIC LIGAND [J].
CHEN, LQ ;
THOMPSON, LK ;
BRIDSON, JN .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1992, 70 (11) :2709-2716
[10]   A simultaneous redox, alkylation, self-assembly reaction under solvothermal conditions afforded a luminescent copper(I) chain polymer constructed of Cu3l4- and EtS-4-C5H4N+Et components (Et = CH3CH2) [J].
Cheng, JK ;
Yao, YG ;
Zhang, J ;
Li, ZJ ;
Cai, ZW ;
Zhang, XY ;
Chen, ZN ;
Chen, YB ;
Kang, Y ;
Qin, YY ;
Wen, YH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (25) :7796-7797