Single crystal investigation of the ternary indides Ce2Pd4In5 and CePdIn4

被引：9
|
作者：
Nesterenko, S. N. [1 ]
Tursina, A. L.
Shtepa, D. V.
Noel, H.
Seropegin, Y. D.
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[2] Univ Rennes 1, CNRS, UMR 6511, Lab Chim Solide & Inorgan Mol, F-35042 Rennes, France
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2007年 / 442卷 / 1-2期
基金：
俄罗斯基础研究基金会;
关键词：
intermetallics; crystal structure; X-ray diffraction;
D O I：
10.1016/j.jallcom.2006.07.135
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The ternary indides Ce2Pd4In5 and CePdIn4 were synthesized by arc-melting of the elements and subsequent annealing at 870 K for 6 weeks. The crystal structures of the compounds were solved from the single crystal X-ray data. Ce2Pd4In5 crystallizes in the new monoclinic structure (space group P2(1)/m, mP22), a = 9.5522(2) angstrom, b = 4.6144(1) angstrom, c = 10.5815(4) angstrom, beta = 102.56 degrees, V = 455.25(10) angstrom(3), Z = 2, R = 0.0302, wR2 = 0.0906 for 2590 reflections. CePdIn4 adopts the YNiAl4 type structure (orthorhombic, Cmcm) a = 4.5351(9) angstrom, b = 16.856(5) angstrom, c = 7.3076(16) angstrom, V = 558.60(3) angstrom(3), Z = 4, R = 0.0349, wR(2) = 0.1075 for 420 reflections. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：93 / 95
页数：3
相关论文
共 50 条
  • [31] Intermediate-valent Cerium in Ce2Ru4Mg17 and a Group-Subgroup Scheme for La9Ru4In5 and Ce9Ru4Ga5
    Linsinger, Stefan
    Hoffmann, Rolf-Dieter
    Eul, Matthias
    Poettgen, Rainer
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2012, 67 (03): : 219 - 225
  • [32] Single crystal investigation of the Yb1-xNi4Sn1+x compound
    Rizzoli, C
    Sologub, OL
    Salamakha, PS
    JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 337 (1-2) : L1 - L3
  • [33] Crystal structure of a Pd-4 carbonyl triphenylphosphane cluster [Pd-4(CO) 5(PPh3)(4)] center dot 2C(4)H(8)O, comparing solvates
    Robeyns, Koen
    Willocq, Christopher
    Tinant, Bernard
    Devillers, Michel
    Hermans, Sophie
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 120 - +
  • [34] The crystal structures of jagueite, Cu2Pd3Se4, and chrisstanleyite, Ag2Pd3Se4
    Topa, Dan
    Makovicky, Emil
    Balic-Zunic, Tonci
    CANADIAN MINERALOGIST, 2006, 44 : 497 - 505
  • [35] Crystal growth and structure of KBi(WO4)2 single crystals
    Xie, Huidong
    Shen, Dezhong
    Xie, Chengzhi
    Wang, Xiaoqing
    Shen, Guangqiu
    CRYSTAL RESEARCH AND TECHNOLOGY, 2006, 41 (10) : 961 - 966
  • [36] Synthesis and crystal structure of 2-amino-4-chloro-5-(4'-methylbenzyl)-6-methylpyrimidine
    Guo Wan-Cheng
    Liu Xing-Hai
    Chen Pei-Quan
    Song Hai-Bin
    Li Zheng-Ming
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (09) : 1005 - 1008
  • [37] Single crystal growth and structure refinement of Li4Ti5O12
    Kataoka, Kunimitsu
    Takahashia, Yasuhiko
    Kijima, Norihito
    Akimoto, Junji
    Ohshima, Ken-ichi
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (5-6) : 1454 - 1456
  • [38] ON THE CRYSTAL-STRUCTURE OF CE-2(WO4)(3)
    GRESSLING, T
    MULLERBUSCHBAUM, H
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (10): : 1513 - 1516
  • [39] Single Crystal Structure and Characterization of 2-Amino-4-methylpyridinium-4-nitrophenolate-4-nitrophenol
    Muralidharan, S.
    Nagapandiselvi, P.
    Srinivasan, T.
    Vidyalakshmi, Y.
    Velmurugan, D.
    Gopalakrishnan, R.
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (18) : 10107 - 10112
  • [40] Growth and investigation on novel single crystal of β-cyclodextrin 2, 4-dinitrophenylhydrazine for optical sensors applications
    Varadarajan, S.
    Saminathan, P.
    Kumar, M. Senthil
    Shanmugan, S.
    Chithambaram, V.
    Gandhimathi, V.
    MATERIALS TODAY-PROCEEDINGS, 2020, 30 : 45 - 51
12345