Single crystal investigation of the ternary indides Ce2Pd4In5 and CePdIn4

被引：9
|
作者：
Nesterenko, S. N. [1 ]
Tursina, A. L.
Shtepa, D. V.
Noel, H.
Seropegin, Y. D.
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[2] Univ Rennes 1, CNRS, UMR 6511, Lab Chim Solide & Inorgan Mol, F-35042 Rennes, France
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2007年 / 442卷 / 1-2期
基金：
俄罗斯基础研究基金会;
关键词：
intermetallics; crystal structure; X-ray diffraction;
D O I：
10.1016/j.jallcom.2006.07.135
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The ternary indides Ce2Pd4In5 and CePdIn4 were synthesized by arc-melting of the elements and subsequent annealing at 870 K for 6 weeks. The crystal structures of the compounds were solved from the single crystal X-ray data. Ce2Pd4In5 crystallizes in the new monoclinic structure (space group P2(1)/m, mP22), a = 9.5522(2) angstrom, b = 4.6144(1) angstrom, c = 10.5815(4) angstrom, beta = 102.56 degrees, V = 455.25(10) angstrom(3), Z = 2, R = 0.0302, wR2 = 0.0906 for 2590 reflections. CePdIn4 adopts the YNiAl4 type structure (orthorhombic, Cmcm) a = 4.5351(9) angstrom, b = 16.856(5) angstrom, c = 7.3076(16) angstrom, V = 558.60(3) angstrom(3), Z = 4, R = 0.0349, wR(2) = 0.1075 for 420 reflections. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：93 / 95
页数：3
相关论文
共 50 条
  • [21] Crystal structure of [NBu4]2[Pd2{C4(COOMe)4}2(μ-OH)2] determined ab initio by charge flipping
    Ortiz, Angel L.
    Cumbrera, Francisco L.
    Perez, Jose
    Melendez-Martinez, Juan J.
    Palatinus, Lukas
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 467 (1-2) : 322 - 326
  • [22] Synthesis and single crystal structures of ternary phosphides Li4SrP2 and AAeP (A = Li, Na;: Ae = Sr, Ba)
    Dong, Yongkwan
    DiSalvo, Francis J.
    JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (02) : 432 - 439
  • [23] Formation, crystal structure and magnetism of ternary compounds Ce5MGe2 (M=Co, Ni, Ru, Rh, Pd, Ir, Pt)
    Sologub, OL
    Salamakha, PS
    Godart, C
    JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 307 (307) : 31 - 39
  • [24] Single crystal investigation of the Yb2Pd1.075(1)Ge6 compound
    Rizzoli, C
    Sologub, O
    Salamakha, P
    JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 351 (1-2) : L10 - L12
  • [25] The crystal structure of a new ternary antimonide:: TmCu4-xSb2 (x=1.065)
    Fedyna, LO
    Bodak, OI
    Fedorchuk, AO
    Tokaychuk, YO
    JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 394 (1-2) : 156 - 159
  • [26] Ternary Antimonides RE2Ir3Sb4 (RE = La, Ce, Pr, Nd)
    Schaefer, Konrad
    Hermes, Wilfried
    Rodewald, Ute Ch.
    Hoffmann, Rolf-Dieter
    Poettgen, Rainer
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2011, 66 (08): : 777 - 783
  • [27] Crystal structure of the Pd(I) carbonyl chloride complex (NH4)2[Pd2Cl4(CO)2]
    Kulik, AV
    Bruk, LG
    Temkin, ON
    Aleksandrov, GG
    Nefedov, SE
    Eremenko, IL
    DOKLADY CHEMISTRY, 2002, 383 (1-3) : 69 - 71
  • [28] Crystal Structure of the Pd(I) Carbonyl Chloride Complex (NH4)2[Pd2Cl4(CO)2]
    A. V. Kulik
    L. G. Bruk
    O. N. Temkin
    G. G. Aleksandrov
    S. E. Nefedov
    I. L. Eremenko
    Doklady Chemistry, 2002, 383 : 69 - 71
  • [29] Rare Earth-Transition Metal Indides with Lu5Ni2In4-type Structure
    Zaremba, Roman
    Hermes, Wilfried
    Eul, Matthias
    Poettgen, Rainer
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2008, 63 (12): : 1447 - 1449
  • [30] Rare earth-nickel-indides Dy5Ni2In4 and RE4Ni11In20 (RE = Gd, Tb, Dy)
    Tyvanchuk, Yuriy B.
    Rodewald, Ute Ch.
    Kalychak, Yaroslav M.
    Poettgen, Rainer
    JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (04) : 878 - 883
12345