O,N-Bidentate Ruthenium Azo Complexes as Catalysts for Olefin Isomerization Reactions

被引：25
|
作者：
Ding, Fu [1 ,2 ]
Sun, Yaguang [2 ]
Verpoort, Francis [1 ]
机构：
[1] Univ Ghent, Dept Inorgan & Phys Chem, Div Organometall & Catalysis, B-9000 Ghent, Belgium
[2] Shenyang Inst Chem Technol, Lab Coordinat Chem, Shenyang 110142, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 10期
关键词：
Isomerization; Olefins; Ruthenium; ASYMMETRIC TRANSFER HYDROGENATION; DOUBLE-BOND MIGRATION; SCHIFF-BASE LIGANDS; CARBENE COMPLEXES; CRYSTAL-STRUCTURE; MECHANISM; METATHESIS; ALLYL; KETONES; ETHERS;
D O I：
10.1002/ejic.200900926
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of ruthenium complexes [(eta(6)-p-cymene)RuCl(L)] [ligands L incorporate an azo group (1-5) or an imino group (6-7)] have been synthesized and studied as olefin isomerization catalyst with allylbenzene and 1-octene as model substrates. Temperature and catalyst/substrate mol ratio have been taken into account as parameters to optimize the isomerization reaction conditions. By using H-1, C-13 NMR, FT-IR and microanalysis, the new complexes have been characterized and the molecular structure of complex 4 has been determined by crystal structure determination.
引用
收藏
页码：1536 / 1543
页数：8
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