Polyaspartic acid based superabsorbent polymers

被引:81
作者
Sharma, Shilpa [1 ]
Dua, Amita [1 ]
Malik, Amita [1 ]
机构
[1] Univ Delhi, Dyal Singh Coll, Dept Chem, New Delhi 110003, India
关键词
Superabsorbent; Polyaspartic acid; Cross-linking; Interpenetrating polymers; Semi-interpenetrating polymers; Grafted polymers; PH-RESPONSIVENESS PROPERTIES; POLY(ASPARTIC ACID); N-ISOPROPYLACRYLAMIDE; SALT-RESPONSIVENESS; SWELLING PROPERTIES; POLY(AMINO ACID)S; HYDROGELS; DEGRADATION; DERIVATIVES; BEHAVIOR;
D O I
10.1016/j.eurpolymj.2014.07.043
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Superabsorbent polymers are widely used in many applications such as disposable diapers, feminine napkins, soil for agriculture and horticulture, gel actuators, water-blocking tapes, drug delivery systems, absorbent pads and other biomedical applications. Most of these superabsorbents are non-biodegradable and thus increasing burden on the earth. Polymer scientist and chemists are looking for environmental friendly solutions. Polyaspartic acid polymers have been reported to possess biodegradable properties. These polymers have been developed mainly as polyelectrolyte. However, this review compiles the work carried on developing polyaspartic acid based superabsorbent polymers. The review covers synthetic methodology, characterization of these polymers by different techniques, different types of polymer prepared using polyaspartic polymers which include co-polymers, grafted polymers, interpenetrating and semi-interpenetrating polymers are covered. The biodegradability studies carried out on the superabsorbent polymers are also discussed. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:363 / 376
页数:14
相关论文
共 65 条
[51]  
Sunita Thombre M, J MACROMOL SCI A
[52]   On the role of urea in chemical evolution of biomolecules, part I. Urea as a nitrogen source in the formation of polyaspartic acid from malic, maleic, and fumaric acids [J].
Terasaki, M ;
Nomoto, S ;
Mita, H ;
Shimoyama, A .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (01) :153-154
[53]   Preparation conditions and properties of biodegradable hydrogels prepared by gamma-irradiation of poly(aspartic acid)s synthesized by thermal polycondensation [J].
Tomida, M ;
Yabe, M ;
Arakawa, Y ;
Kunioka, M .
POLYMER, 1997, 38 (11) :2791-2795
[54]  
Tudorachi N, 2010, POLIMERY-W, V55, P562
[55]   Novel solvent-free synthesis and modification of polyaspartic acid hydrogel [J].
Wang, Yuming ;
Xue, Mingyuan ;
Wei, Jun ;
Li, Chunling ;
Zhang, Rui ;
Cao, Hui ;
Yang, Jing ;
Tan, Tianwei .
RSC ADVANCES, 2012, 2 (30) :11592-11600
[56]   Thermoreversible swelling behaviour of hydrogels based on N-isopropylacrylamide with a zwitterionic comonomer [J].
Xue, W ;
Champ, S ;
Huglin, MB .
EUROPEAN POLYMER JOURNAL, 2001, 37 (05) :869-875
[57]  
Yoshihro I, 1998, Eur Pat Appl, Patent No. [EP866084, 866084]
[58]   Superabsorbent hydrogels from poly(aspartic acid) with salt-, temperature- and pH-responsiveness properties [J].
Zhao, Y ;
Su, HJ ;
Fang, L ;
Tan, TW .
POLYMER, 2005, 46 (14) :5368-5376
[59]   Salt-, pH- and temperature-responsive semi-interpenetrating polymer network hydrogel based on poly(aspartic acid) and poly(acrylic acid) [J].
Zhao, Ying ;
Kang, Juan ;
Tan, Tianwei .
POLYMER, 2006, 47 (22) :7702-7710
[60]   Study on superabsorbent composite XVI. Synthesis, characterization and swelling behaviors of poly(sodium acrylate)/vermiculite superabsorbent composites [J].
Zheng, Yian ;
Li, Ping ;
Zhang, Junping ;
Wang, Aiqin .
EUROPEAN POLYMER JOURNAL, 2007, 43 (05) :1691-1698