Supramolecular self-assembled calix[4]arene xanthate-Ni2+ complex compound

被引：0

作者：

Yang, FF ^{[1
]}

Chen, XL

Cai, XQ

Lin, S

Chen, YY

机构：

[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[3] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 20卷 / 09期

关键词：

calix[4]arene; xanthate; self-assembled; Ni2+ complex;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under the action of CS2 and KOH in dioxane solution, calix[4]arene derivative 2 was converted into calix[4] arene derivative containing xanthate salt (3) and its Ni2+ complex compound 4 was prepared by self-assembled reaction with NiSO4 further. The structures of new compounds were confirmed by elemental analyses, IR, UV, H-1 NMR, MS techniques. The Ni2+ of complex compound 4 was in high-spin state by its ESR spectrum.

引用

页码：1081 / 1084

页数：4

共 12 条

[1] Self-assembled xanthate-transition metal polyether macrocycles and cryptands
Beer, PD
Cowley, AR
Jeffery, JC
Paul, RL
Wong, WWH
[J]. POLYHEDRON, 2003, 22 (05) : 795 - 801
[2] Synthesis of a novel three-coordinate copper(I) complex: a structural mimic of the reduced form of type 1 site in copper protein
Cao, YD
Zheng, QY
Chen, CF
Hu, HM
Huang, ZT
[J]. INORGANICA CHIMICA ACTA, 2004, 357 (01) : 316 - 320
[3] Dalbavie JO, 2000, EUR J INORG CHEM, P683
[4] Metal-directed self-assembly of two- and three-dimensional synthetic receptors
Fujita, M
[J]. CHEMICAL SOCIETY REVIEWS, 1998, 27 (06) : 417 - 425
[5] Upper-rim functionalization of calix[4]arene by chloro(isocyanide)gold(I) groups: An entry polymetallic architecture
Gagnon, J
Drouin, M
Harvey, PD
[J]. INORGANIC CHEMISTRY, 2001, 40 (23) : 6052 - 6056
[6] Guan H., 1999, J FUNCTIONAL POLYM, V12, P431
[7] Selective binding of trivalent metals by hexahomotrioxacalix[3]arene macrocycles: Determination of metal-binding constants and metal transport studies
Hampton, PD
Daitch, CE
Shachter, AM
[J]. INORGANIC CHEMISTRY, 1997, 36 (14) : 2956 - 2959
[8] Self-assembly of discrete cyclic nanostructures mediated by transition metals
Leininger, S
Olenyuk, B
Stang, PJ
[J]. CHEMICAL REVIEWS, 2000, 100 (03) : 853 - 907
[9] A calix[4]arene-porphyrinatozinc conjugate which features the cooperative action of a cation-π interaction and metal coordination
Nakamura, R
Ikeda, A
Sarson, LD
Shinkai, S
[J]. SUPRAMOLECULAR CHEMISTRY, 1998, 9 (01) : 25 - 29
[10] Spin structures and properties of paramagnetic nickel(II) complexes with liquid crystalline beta-diketone ligands
Piao, G
Akagi, K
Shirakawa, H
[J]. SYNTHETIC METALS, 1997, 85 (1-3) : 1669 - 1670

← 1 2 →