Sensitive determination of baicalein based on functionalized graphene loaded RuO2 nanoparticles modified glassy carbon electrode

被引：22

作者：

Qiao, Jiantong ^{[1
]}

Zhang, Yulong ^{[1
]}

Lei, Sheng ^{[1
]}

Liu, Zi ^{[1
]}

Li, Gaiping ^{[1
]}

Ye, Baoxian ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

TALANTA | 2018年 / 188卷

基金：

中国国家自然科学基金;

关键词：

Baicalein; Reduced graphene oxide; RuO2; DPV; Electrochemical sensor; SCUTELLARIAE-RADIX; MAJOR FLAVONOIDS; LIQUID; OXIDE; PLATFORM; CHRYSIN; CELLS; ACID;

D O I：

10.1016/j.talanta.2018.06.047

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The nanocomposite of ruthenium oxide (RuO2) loaded on Poly-(dimethyldiallylammonium chloride) (PDDA) functionalized reduced graphene oxide (RuO2-PDDA-rGO) was synthesized based on a one-step method. Based on the RuO2-PDDA-rGO modified glassy carbon electrode (GCE), a new electrochemical sensor (RuO2-PDDA-rGO/GCE) was fabricated and used in detection of baicalein for the first time. Compared with other reported electrochemical sensors for the detection of baicalein, the prepared RuO2-PDDA-rGO/GCE had a wider linear range (2-400 nM) and lower detection limit (0.6 nM, S/N = 3). The other advantages were the excellent repeatability of proposed method and good stability of prepared sensor.

引用

页码：714 / 721

页数：8

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