Coupling of organometallic reaction centers through the non-planar bridging ligand 2,3-bis(2-pyridyl)pyrazine

被引：4
作者：
Berger, S
Scheiring, T
Fiedler, J
Kaim, W
机构：
[1] Univ Stuttgart, Inst Anorgan Chem, D-70550 Stuttgart, Germany
[2] J Heyrovsky Inst Phys Chem & Electrochem, CR-18223 Prague, Czech Republic
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 13-14期
关键词：
crystal structure; eletrochemistry; iridium; rhodium; UV/vis-spectroscopy;
D O I：
10.1002/zaac.200400133
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The widely used ligand 2,3-bppz = 2,3-bis(2-pyridyl)pyrazine and the complexes [(2,3-bppz){(C5Me5)ClM}(11)](PF6)(n), M = Rh or Ir and n = 1 or 2, were investigated by cyclic voltammetry and UV/VIS-spectroelectrochemistry. For both the mononuclear and, unusually, the dinuclear complexes we observed only chloride-dissociative two-electron reduction processes. One of the precursor complexes, [(2,3-bppz)(C5Me5)ClIr]Cl.2H(2)O, was structurally characterized and found to contain a considerably nonplanar 2,3-bppz ligand.
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收藏
页码：2409 / 2417
页数：9
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