Can Online Aerosol Mass Spectrometry Analysis Classify Secondary Organic Aerosol (SOA) and Oxidized Primary Organic Aerosol (OPOA)? A Case Study of Laboratory and Field Studies of Indonesian Biomass Burning

被引:12
作者
Budisulistiorini, Sri Hapsari [3 ,5 ]
Chen, Jing [1 ,2 ,3 ]
Itoh, Masayuki [4 ]
Kuwata, Mikinori [2 ,3 ,6 ,7 ]
机构
[1] Chongqing Univ, Coll Environm & Ecol, Chongqing 400044, Peoples R China
[2] Nanyang Technol Univ, Earth Observ Singapore, Singapore 639798, Singapore
[3] Campus Res Excellence & Technol Enterprise CREATE, Singapore 138602, Singapore
[4] Univ Hyogo, Sch Human Sci & Environm, Himeji, Hyogo 6700092, Japan
[5] Univ York, Wolfson Atmospher Chem Labs, York YO10 5DD, N Yorkshire, England
[6] Peking Univ, Dept Atmospher & Ocean Sci, Sch Phys, Beijing 100871, Peoples R China
[7] Peking Univ, Beijing Innovat Ctr Engn Sci & Adv Technol BIC ES, Beijing 100871, Peoples R China
来源
ACS EARTH AND SPACE CHEMISTRY | 2021年 / 5卷 / 12期
基金
新加坡国家研究基金会;
关键词
mass spectra; high molecular weight species ions; organic aerosol; biomass burning; photooxidation; flow reactor; factor analysis; CHEMICAL-COMPOSITION; SOURCE APPORTIONMENT; PARTICULATE MATTER; HYDROCARBON-LIKE; EMISSIONS; COMPONENTS; AIRCRAFT; SMOKE; PHOTOOXIDATION; QUANTIFICATION;
D O I
10.1021/acsearthspacechem.1c00319
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organic aerosol (OA) makes up a significant fraction of ambient particulate matter, including those emitted during the wildfire. Oxidized organic aerosol (OOA), obtained by factor analysis, dominates OA as the air mass ages. OOA includes secondary organic aerosol (SOA) and oxidized primary organic aerosol (OPOA). OPOA and SOA formations affect the OA scheme in the chemical models. Thus, their identification is essential. We aim to test the capability of the online aerosol mass spectrometry analysis to identify SOA and OPOA through laboratory studies. First, we separated particle- and gas-phase species emitted from the combustion of Indonesian peat and biomasses. Then, they were reacted in an oxidation reactor, where a time-of-flight aerosol chemical speciation monitor measured the oxidation products. Factor analysis was used to identify OPOA from the measured OA. We examined OPOA and SOA characteristics using the widely used fractional contributions of ion signal at mass-to-charge ratios (m/z's) 44 and 43 (f(44) vs f(43)) and m/z's 44 and 60 (f(44) vs f(60)). The OPOA and SOA were found to be indistinguishable. However, by examining all ions, particularly, the higher molecular weight species (m/z >= 100), we could differentiate the OPOA from some SOA. Additionally, OPOA and SOA mass spectra were compared to the ambient OOA factor observed in Singapore during the Indonesian wildfire in 2015. The comparison suggested that the observed OOA contained a mixture of SOA and OPOA. This study underlines the advantage of using detailed chemical information for characterizing OPOA and SOA in future development.
引用
收藏
页码:3511 / 3522
页数:12
相关论文
共 61 条
  • [11] Direct observation of aqueous secondary organic aerosol from biomass-burning emissions
    Gilardoni, Stefania
    Massoli, Paola
    Paglione, Marco
    Giulianelli, Lara
    Carbone, Claudio
    Rinaldi, Matteo
    Decesari, Stefano
    Sandrini, Silvia
    Costabile, Francesca
    Gobbi, Gian Paolo
    Pietrogrande, Maria Chiara
    Visentin, Marco
    Scotto, Fabiana
    Fuzzi, Sandro
    Facchini, Maria Cristina
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2016, 113 (36) : 10013 - 10018
  • [12] Estimated contributions of primary and secondary organic aerosol from fossil fuel combustion during the CalNex and Cal-Mex campaigns
    Guzman-Morales, J.
    Frossard, A. A.
    Corrigan, A. L.
    Russell, L. M.
    Liu, S.
    Takahama, S.
    Taylor, J. W.
    Allan, J.
    Coe, H.
    Zhao, Y.
    Goldstein, A. H.
    [J]. ATMOSPHERIC ENVIRONMENT, 2014, 88 : 330 - 340
  • [13] The formation, properties and impact of secondary organic aerosol: current and emerging issues
    Hallquist, M.
    Wenger, J. C.
    Baltensperger, U.
    Rudich, Y.
    Simpson, D.
    Claeys, M.
    Dommen, J.
    Donahue, N. M.
    George, C.
    Goldstein, A. H.
    Hamilton, J. F.
    Herrmann, H.
    Hoffmann, T.
    Iinuma, Y.
    Jang, M.
    Jenkin, M. E.
    Jimenez, J. L.
    Kiendler-Scharr, A.
    Maenhaut, W.
    McFiggans, G.
    Mentel, Th. F.
    Monod, A.
    Prevot, A. S. H.
    Seinfeld, J. H.
    Surratt, J. D.
    Szmigielski, R.
    Wildt, J.
    [J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2009, 9 (14) : 5155 - 5236
  • [14] High Time- and Size-Resolved Measurements of PM and Chemical Composition from Coal Combustion: Implications for the EC Formation Process
    Han, Yong
    Chen, Yingjun
    Ahmad, Saud
    Feng, Yanli
    Zhang, Fan
    Song, Wenhuai
    Cao, Fang
    Zhang, Yanlin
    Yang, Xin
    Li, Jun
    Zhang, Gan
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2018, 52 (11) : 6676 - 6685
  • [15] A simplified description of the evolution of organic aerosol composition in the atmosphere
    Heald, C. L.
    Kroll, J. H.
    Jimenez, J. L.
    Docherty, K. S.
    DeCarlo, P. F.
    Aiken, A. C.
    Chen, Q.
    Martin, S. T.
    Farmer, D. K.
    Artaxo, P.
    [J]. GEOPHYSICAL RESEARCH LETTERS, 2010, 37
  • [16] CHEMICAL-COMPOSITION OF EMISSIONS FROM URBAN SOURCES OF FINE ORGANIC AEROSOL
    HILDEMANN, LM
    MARKOWSKI, GR
    CASS, GR
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1991, 25 (04) : 744 - 759
  • [17] Modeling organic aerosols in a megacity: potential contribution of semi-volatile and intermediate volatility primary organic compounds to secondary organic aerosol formation
    Hodzic, A.
    Jimenez, J. L.
    Madronich, S.
    Canagaratna, M. R.
    DeCarlo, P. F.
    Kleinman, L.
    Fast, J.
    [J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2010, 10 (12) : 5491 - 5514
  • [18] Modeling the formation and properties of traditional and non-traditional secondary organic aerosol: problem formulation and application to aircraft exhaust
    Jathar, S. H.
    Miracolo, M. A.
    Presto, A. A.
    Donahue, N. M.
    Adams, P. J.
    Robinson, A. L.
    [J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2012, 12 (19) : 9025 - 9040
  • [19] Evolution of Organic Aerosols in the Atmosphere
    Jimenez, J. L.
    Canagaratna, M. R.
    Donahue, N. M.
    Prevot, A. S. H.
    Zhang, Q.
    Kroll, J. H.
    DeCarlo, P. F.
    Allan, J. D.
    Coe, H.
    Ng, N. L.
    Aiken, A. C.
    Docherty, K. S.
    Ulbrich, I. M.
    Grieshop, A. P.
    Robinson, A. L.
    Duplissy, J.
    Smith, J. D.
    Wilson, K. R.
    Lanz, V. A.
    Hueglin, C.
    Sun, Y. L.
    Tian, J.
    Laaksonen, A.
    Raatikainen, T.
    Rautiainen, J.
    Vaattovaara, P.
    Ehn, M.
    Kulmala, M.
    Tomlinson, J. M.
    Collins, D. R.
    Cubison, M. J.
    Dunlea, E. J.
    Huffman, J. A.
    Onasch, T. B.
    Alfarra, M. R.
    Williams, P. I.
    Bower, K.
    Kondo, Y.
    Schneider, J.
    Drewnick, F.
    Borrmann, S.
    Weimer, S.
    Demerjian, K.
    Salcedo, D.
    Cottrell, L.
    Griffin, R.
    Takami, A.
    Miyoshi, T.
    Hatakeyama, S.
    Shimono, A.
    [J]. SCIENCE, 2009, 326 (5959) : 1525 - 1529
  • [20] High-molecular-weight esters in α-pinene ozonolysis secondary organic aerosol: structural characterization and mechanistic proposal for their formation from highly oxygenated molecules
    Kahnt, Ariane
    Vermeylen, Reinhilde
    Iinuma, Yoshiteru
    Shalamzari, Mohammad Safi
    Maenhaut, Willy
    Claeys, Magda
    [J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2018, 18 (11) : 8453 - 8467