Water-Lean Solvents for Post-Combustion CO2 Capture: Fundamentals, Uncertainties, Opportunities, and Outlook

被引：302

作者：

Heldebrant, David J. ^{[1
]}

Koech, Phillip K. ^{[1
]}

Glezakou, Vassiliki-Alexandra ^{[1
]}

Rousseau, Roger ^{[1
]}

Malhotra, Deepika ^{[1
]}

Cantu, David C. ^{[1
]}

机构：

[1] Pacific Northwest Natl Lab, 902 Battelle Blvd, Richland, WA 99352 USA

来源：

CHEMICAL REVIEWS | 2017年 / 117卷 / 14期

基金：

美国能源部;

关键词：

CARBON-DIOXIDE ABSORPTION; MOLECULAR-DYNAMICS SIMULATIONS; CO2-BINDING ORGANIC LIQUIDS; TEMPERATURE IONIC LIQUIDS; GLYCOL PLUS WATER; HIGHLY EFFICIENT; AQUEOUS-SOLUTIONS; MONTE-CARLO; ETHYLENE-GLYCOL; SO2; CAPTURE;

D O I：

10.1021/acs.chemrev.6b00768

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review is designed to foster the discussion regarding the viability of postcombustion CO2 capture by water-lean solvents, by separating fact from fiction for both skeptics and, advocates. We highlight the unique physical and thermodynamic properties of notable water-lean solvents, with a discussion of how such properties could translate to efficiency gains compared to aqueous amines. The scope of this review ranges from the purely fundamental molecular-level processes that govern solvent behavior to bench-scale testing, through "process engineering and projections of process performance and cost. Key discussions of higher than expected CO2 mass transfer, water tolerance, and compatibility with current infrastructure are presented along with current limitations and suggested areas where further solvent development is needed. We conclude with an outlook of the status of the field and assess the viability of water-lean solvents for postcombustion CO2 capture.

引用

页码：9594 / 9624

页数：31

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