Oxidation of primary alcohols by quinolinium dichromate. A kinetic probe

被引：0
|
作者：
Nongkynrih, I. [1 ]
Dkhar, J. C. [1 ]
Kharpuria, E. [1 ]
Mahanti, M. K. [1 ]
机构：
[1] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India
来源：
OXIDATION COMMUNICATIONS | 2007年 / 30卷 / 01期
关键词：
primary alcohols; quinolinium dichromate; oxidation; mechanism;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The oxidation of primary alcohols by quinolinium dichromate, in acid medium, gave the corresponding aldehydes. The reaction was first order in each - substrate, oxidant and acid. The mechanistic pathway involved the formation of a cyclic chromate ester, which underwent decomposition, in the rate-determining step, to give the product.
引用
收藏
页码：82 / 87
页数：6
相关论文
共 50 条
  • [41] OXIDATION OF CARBONACEOUS MATERIALS BY A SOLUTION OF POTASSIUM DICHROMATE.
    Chirkina, A.P.
    Naumova, G.V.
    Mashkovich, L.A.
    Cherednik, E.M.
    Kuteinikov, A.F.
    Solid Fuel Chemistry, 1986, 20 (05) : 88 - 91
  • [42] Peroxydase catalysed oxidation of alcohols and aliphatic amines by quinolinium dichromate in aqueous buffer and micellar media : A kinetic study.
    Rajanna, KC
    Humaira, T
    Kumar, UU
    Sundari, LBT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U394 - U394
  • [43] Oxidation of α, β-unsaturated alcohols by nicotinium dichromate:: A kinetic study
    Sekar, KG
    ASIAN JOURNAL OF CHEMISTRY, 2003, 15 (01) : 423 - 427
  • [44] Kinetics of quinolinium dichromate oxidation of triols
    Nongkynrih, I.
    Mahanti, M. K.
    OXIDATION COMMUNICATIONS, 2007, 30 (03): : 601 - 606
  • [45] Kinetics of oxidation of carbinols by quinolinium dichromate
    Nongkynrih, I.
    Mahanti, M. K.
    OXIDATION COMMUNICATIONS, 2007, 30 (03): : 587 - 592
  • [46] Kinetics of oxidation of benzaldehydes by quinolinium dichromate
    Medien, HAA
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2003, 58 (12): : 1201 - 1205
  • [47] Kinetics of oxidation of diols by quinolinium dichromate
    Debroy, A
    Mahanti, MK
    OXIDATION COMMUNICATIONS, 1996, 19 (02): : 251 - 257
  • [48] Kinetics of the oxidation of salicylaldehydes by quinolinium dichromate
    Chaubey, G. S.
    Mahanti, M. K.
    OXIDATION COMMUNICATIONS, 2006, 29 (02): : 290 - 297
  • [49] Enhanced reactivity in the oxidation of cyclanones by pyridinium dichromate.
    Ravishankar, M
    Sekar, KG
    Palaniappan, AN
    AFINIDAD, 2004, 61 (512) : 323 - 327
  • [50] KINETICS OF OXIDATION OF FLUORENE BY QUINOLINIUM DICHROMATE
    SARMA, GC
    MAHANTI, MK
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1991, (04): : 449 - 453
12345