Oxidation of primary alcohols by quinolinium dichromate. A kinetic probe

被引：0
|
作者：
Nongkynrih, I. [1 ]
Dkhar, J. C. [1 ]
Kharpuria, E. [1 ]
Mahanti, M. K. [1 ]
机构：
[1] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India
来源：
OXIDATION COMMUNICATIONS | 2007年 / 30卷 / 01期
关键词：
primary alcohols; quinolinium dichromate; oxidation; mechanism;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The oxidation of primary alcohols by quinolinium dichromate, in acid medium, gave the corresponding aldehydes. The reaction was first order in each - substrate, oxidant and acid. The mechanistic pathway involved the formation of a cyclic chromate ester, which underwent decomposition, in the rate-determining step, to give the product.
引用
收藏
页码：82 / 87
页数：6
相关论文
共 50 条
  • [21] Quinolinium dichromate oxidation of diols: A kinetic study
    Kuotsu, B
    Tiewsoh, E
    Debroy, A
    Mahanti, MK
    JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (25): : 8875 - 8877
  • [22] NONLINEAR HAMMETTS RELATIONSHIP IN THE OXIDATION OF BENZYL ALCOHOLS BY QUINOLINIUM DICHROMATE - A KINETIC-STUDY
    ARUNA, K
    MANIKYAMBA, P
    SUNDARAM, EV
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1994, 33 (09): : 854 - 856
  • [23] The photochemical oxidation of alcohols by potassium dichromate. Part III.
    Bowen, EJ
    Peacocke, TA
    Wellburn, ER
    JOURNAL OF THE CHEMICAL SOCIETY, 1931, : 1866 - 1870
  • [24] Kinetics and mechanism of oxidation of allylic alcohols by quinolinium dichromate
    Kharpuria, E
    Nongkynrih, I
    Mahanti, MK
    OXIDATION COMMUNICATIONS, 1996, 19 (02): : 258 - 264
  • [25] KINETICS OF OXIDATION OF SUBSTITUTED BENZYL ALCOHOLS BY QUINOLINIUM DICHROMATE
    DEY, D
    MAHANTI, MK
    JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (23): : 5848 - 5850
  • [26] Kinetic studies on the oxidation of aliphatic aldehydes by quinolinium dichromate
    Chaubey, GS
    Das, S
    Mahanti, MK
    OXIDATION COMMUNICATIONS, 2003, 26 (04): : 526 - 531
  • [27] Quinolinium dichromate oxidation of aliphatic aldehydes: A kinetic study
    Chaubey, GS
    Das, S
    Mahanti, MK
    CROATICA CHEMICA ACTA, 2003, 76 (04) : 287 - 291
  • [28] Kinetic features of the quinolinium dichromate oxidation of unsaturated aldehydes
    Chaubey, G. S.
    Mahanti, M. K.
    OXIDATION COMMUNICATIONS, 2006, 29 (02): : 281 - 289
  • [29] Oxidation of heterocyclic aldehydes by quinolinium dichromate: A kinetic study
    Chaubey, GS
    Das, S
    Mahanti, MK
    HETEROCYCLIC COMMUNICATIONS, 2002, 8 (05) : 497 - 500
  • [30] Kinetic features of the oxidation of aliphatic dialdehydes by quinolinium dichromate
    Chaubey, GS
    Susngi, A
    Das, S
    Mahanti, MK
    KINETICS AND CATALYSIS, 2002, 43 (06) : 789 - 793
12345