Oxidation of primary alcohols by quinolinium dichromate. A kinetic probe

被引：0
|
作者：
Nongkynrih, I. [1 ]
Dkhar, J. C. [1 ]
Kharpuria, E. [1 ]
Mahanti, M. K. [1 ]
机构：
[1] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India
来源：
OXIDATION COMMUNICATIONS | 2007年 / 30卷 / 01期
关键词：
primary alcohols; quinolinium dichromate; oxidation; mechanism;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The oxidation of primary alcohols by quinolinium dichromate, in acid medium, gave the corresponding aldehydes. The reaction was first order in each - substrate, oxidant and acid. The mechanistic pathway involved the formation of a cyclic chromate ester, which underwent decomposition, in the rate-determining step, to give the product.
引用
收藏
页码：82 / 87
页数：6
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