Syntheses and electronic behaviors of net-worked, alternating hafnium-organic moiety hybrid copolymers

被引：2

作者：

Matsui, Hideo

Okada, Akira

Kuroda, Taketoshi

Seguchi, Yasuhiro

Kawahara, Tetsuro

Yoshihara, Masakuni

机构：

[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Osaka 5778562, Japan

[2] Nippon Sheet Glass Co Ltd, Minato Ku, Tokyo 1058552, Japan

[3] Kinki Univ, Mol Engn Inst, Osaka 5778502, Japan

来源：

JOURNAL OF MATERIALS SCIENCE | 2007年 / 42卷 / 11期

关键词：

D O I：

10.1007/s10853-006-0352-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Hafnium-organic moiety hybrid copolymers were prepared by reacting hafnium n-butoxide with organic diols. ESR spectral examinations of copolymers and ab-initio calculations of copolymer models suggest that an electron transfer from organic group to hafnium atom takes place.

引用

页码：3964 / 3968

页数：5

共 15 条

[1] OXIDATION REDUCTION REACTIONS FOR PREPARATION OF [TI(OC6H4O)2]N AND RELATED METALLOQUINONE POLYMERS - HYBRID INORGANIC ORGANIC METAL-OXIDES [J].

BURCH, RR .

CHEMISTRY OF MATERIALS, 1990, 2 (06) :633-635

[2]

Cho JW, 2001, POLYMER, V42, P727, DOI 10.1016/S0032-3861(00)00371-2

[3]

HAGRMAN D, 1971, J INORG CHEM, V10, P2091

[4] An infinite 2D polyrotaxane network in Ag-2(bix)(3)(NO3)(2) (bix equals 1,4-bis(imidazol-1-ylmethyl)benzene) [J].

Hoskins, BF ;

Robson, R ;

Slizys, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (12) :2952-2953

[5]

KUDO R, 2002, J CHEM SOC JPN, V3, P371

[6] Syntheses and electronic behaviors of networked alternating neodymium-organic moiety hybrid copolymers [J].

Matsui, H ;

Otsuki, K ;

Yoshihara, M .

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2005, A42 (05) :633-639

[7] Syntheses and electron transfer behavior of novel net-worked alternative zirconium-organic moieties hybrid copolymers [J].

Matsui, H ;

Okada, A ;

Takeuchi, T ;

Yoshihara, M .

ELECTROCHEMISTRY, 2002, 70 (11) :842-846

[8] Syntheses of novel net-worked alternative titanium-organic hybrid copolymers [J].

Matsui, H ;

Okada, A ;

Yoshihara, M .

JOURNAL OF MATERIALS SCIENCE LETTERS, 2001, 20 (12) :1151-1153

[9] Syntheses of novel networked alternating silicon-organic moieties hybrid copolymers [J].

Otsuki, K ;

Okabe, M ;

Matsui, H ;

Yoshihara, M .

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2004, A41 (11) :1303-1310

[10]

Stein A, 2000, ADV MATER, V12, P1403, DOI 10.1002/1521-4095(200010)12:19<1403::AID-ADMA1403>3.0.CO

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