Preparation of Hybrid Ion Exchanger Based on Acrylamide for Sorption of Some Toxic Metal Ions from Aqueous Waste Solutions

被引：11
作者：
Abdel-Galil, E. A. [1 ]
El-Deen, G. E. Sharaf [1 ]
El-Aryan, Y. F. [1 ]
Khalil, M. [1 ]
机构：
[1] Atom Energy Author, Hot Lab Ctr, Cairo 13759, Egypt
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2016年 / 89卷 / 03期
关键词：
SELECTIVE MEMBRANE-ELECTRODE; INORGANIC COMPOSITE-MATERIAL; CATION-EXCHANGER; CERIUM(IV) ANTIMONATE; TH(IV) PHOSPHATE; ZIRCONIUM; ADSORPTION; SILICATE; THERMODYNAMICS; SEPARATION;
D O I：
10.1134/S10704272160030198
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Crystalline phases of polyacrylamide titanium tungstophosphate composite material has been synthesized via sol-gel method. The properties of its were determined using different technique. The ion-exchange capacities of the hybrid material for Cs+, Co2+ and Eu3+ ions it was found that 6.22, 2.76 and 1.38 mequiv.g(-1) respectively. The material was found that highly selective for Eu3+ and the selectivity sequence for sorption of Cs+, Co2+ and Eu3+ ions on polyacrylamide titanium tungstophosphate was found that; Eu3+ > Cs+ > Co2+. Thermodynamic parameters have been calculated for the studied ions showing that the overall adsorption process is spontaneous and endothermic. The experimental isotherm data were analyzed using the Langmuir and Freundlich models.
引用
收藏
页码：467 / 479
页数：13
相关论文
共 51 条
  • [1] Thermodynamic modeling for the removal of Cs+, Sr2+, Ca2+ and Mg2+ ions from aqueous waste solutions using zeolite A
    Abd El-Rahman, K. M.
    El-Kamash, A. M.
    El-Sourougy, M. R.
    Abdel-Moniem, N. M.
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2006, 268 (02) : 221 - 230
  • [2] Abdel-Galil E. A., THESIS
  • [3] Chemical deposition of zirconium doped tin silicate ion-exchanger and its characterization
    Abou-Mesalam, M. M.
    El-Naggar, I. M.
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2009, 279 (01) : 333 - 340
  • [4] STOICHEIOMETRY OF ION EXCHANGE MATERIALS CONTAINING ZIRCONIUM AND PHOSPHATE
    ALBERTI, G
    TORRACCA, E
    CONTE, A
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1966, 28 (02): : 607 - &
  • [5] Synthesis, structure, dehydration transformations and ion exchange characteristics of iron-silicate with various Si and Fe contents as mixed oxides
    Ali, I. M.
    Zakaria, E. S.
    Ibrahim, M. M.
    El-Naggar, I. M.
    [J]. POLYHEDRON, 2008, 27 (01) : 429 - 439
  • [6] Altin O., 2008, J COLLOID INTERF SCI, V198, P130
  • [7] Adsorption of some hazardous radionuclides on cerium(IV) antimonate
    Aly, HF
    Zakaria, ES
    Shady, SA
    El-Naggar, IM
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 1999, 241 (02) : 331 - 336
  • [8] Heavy metal adsorption by modified oak sawdust: Thermodynamics and kinetics
    Argun, Mehmet Emin
    Dursun, Sukru
    Ozdemir, Celalettin
    Karatas, Mustafa
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2007, 141 (01) : 77 - 85
  • [9] The ion exchange properties and equilibrium constants of Li+, Na+ and K+ on zirconium phosphate highly dispersed on a cellulose acetate fibers surface
    Borgo, CA
    Lazarin, AM
    Kholin, YV
    Landers, R
    Gushikem, Y
    [J]. JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2004, 15 (01) : 50 - 57
  • [10] Clark A., 1970, The Theory of Adsorption and Catalysis
123456