The synthesis of palladium-gold and platinum-gold bimetallic complexes based upon tripod tridentate phosphine and arsine ligands

被引：6

作者：

Chiffey, AF ^{[1
]}

Evans, J ^{[1
]}

Levason, W ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND

来源：

POLYHEDRON | 1996年 / 15卷 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0277-5387(95)00382-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The planar complexes MLCl(2) [M = Pd or Pt; L = MeC(CH(2)PPh(2))(3), MC (CH(2)AsPh(2))(3), MeC(CH(2)AsMe(2))(3), MeC(CH(2)SMe)(3) or MeC(CH(2)SeMe)(3)] have been prepared. In all cases spectroscopic data show that the tripod ligands are coordinated as cis bidentates. The complexes of MeC(CH(2)PPh(2))(3) and MeC(CH(2)AsPh(2))(3) react with AuCl(SMe(2)) in CH2Cl2 to form bimetallics MLAuCl(3) with the gold coordinated to the third donor group. All five tridentates react with Au(SMe(2))Cl or Au(tetrahydrothiophen) Cl to form L(AuCl)(3) complexes.

引用

页码：1309 / 1314

页数：6

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